[H 5PMo VI 8V IV 4O 40(V IVO) 2]·8H 2O: Confinement of heteropoly anions in Ni-containing rigid concave surfaces with high catalytic activity in the oxidation of styrene

Jie Fu; Haixia Sun; Yan Xu; Congling Wang; Dunru Zhu; Qi Sun; Hongke Liu

doi:10.1039/c2ce25419k

[H ₅PMo ^VI ₈V ^IV ₄O ₄₀(V ^IVO) ₂]·8H ₂O: Confinement of heteropoly anions in Ni-containing rigid concave surfaces with high catalytic activity in the oxidation of styrene

Jie Fu, Haixia Sun, Yan Xu, Congling Wang, Dunru Zhu, Qi Sun, Hongke Liu

College of Chemical Engineering

Research output: Contribution to journal › Article › peer-review

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Abstract

An organic-inorganic hybrid solid material, [Ni(m-bitmb) ₄][H ₅PMo ^VI ₈V ^IV ₄O ₄₀(V ^IVO) ₂]·8H ₂O (m-bitmb = 1, 3-bis (1-imidazol-1-ylmethyl)-2,4,6-trimethylbenzene) 1, constructed from a bi-capped Keggin structural anion [H ₅PMo ^VI ₈V ^IV ₄O ₄₀(V ^IVO) ₂] ^2- (abbreviated as PMo ₈V ₆), and saddle shape cluster [Ni(m-bitmb) ₄] ²⁺, has been synthesized. Compound 1 is also demonstrated to be a high activity for benzaldehyde in the oxidation of styrene.

Original language	English
Pages (from-to)	5148-5150
Number of pages	3
Journal	CrystEngComm
Volume	14
Issue number	16
DOIs	https://doi.org/10.1039/c2ce25419k
State	Published - 21 Aug 2012

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title = "[H 5PMo VI 8V IV 4O 40(V IVO) 2]·8H 2O: Confinement of heteropoly anions in Ni-containing rigid concave surfaces with high catalytic activity in the oxidation of styrene",

abstract = "An organic-inorganic hybrid solid material, [Ni(m-bitmb) 4][H 5PMo VI 8V IV 4O 40(V IVO) 2]·8H 2O (m-bitmb = 1, 3-bis (1-imidazol-1-ylmethyl)-2,4,6-trimethylbenzene) 1, constructed from a bi-capped Keggin structural anion [H 5PMo VI 8V IV 4O 40(V IVO) 2] 2- (abbreviated as PMo 8V 6), and saddle shape cluster [Ni(m-bitmb) 4] 2+, has been synthesized. Compound 1 is also demonstrated to be a high activity for benzaldehyde in the oxidation of styrene.",

author = "Jie Fu and Haixia Sun and Yan Xu and Congling Wang and Dunru Zhu and Qi Sun and Hongke Liu",

year = "2012",

month = aug,

day = "21",

doi = "10.1039/c2ce25419k",

language = "英语",

volume = "14",

pages = "5148--5150",

journal = "CrystEngComm",

issn = "1466-8033",

publisher = "Royal Society of Chemistry",

number = "16",

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TY - JOUR

T1 - [H 5PMo VI 8V IV 4O 40(V IVO) 2]·8H 2O

T2 - Confinement of heteropoly anions in Ni-containing rigid concave surfaces with high catalytic activity in the oxidation of styrene

AU - Fu, Jie

AU - Sun, Haixia

AU - Xu, Yan

AU - Wang, Congling

AU - Zhu, Dunru

AU - Sun, Qi

AU - Liu, Hongke

PY - 2012/8/21

Y1 - 2012/8/21

N2 - An organic-inorganic hybrid solid material, [Ni(m-bitmb) 4][H 5PMo VI 8V IV 4O 40(V IVO) 2]·8H 2O (m-bitmb = 1, 3-bis (1-imidazol-1-ylmethyl)-2,4,6-trimethylbenzene) 1, constructed from a bi-capped Keggin structural anion [H 5PMo VI 8V IV 4O 40(V IVO) 2] 2- (abbreviated as PMo 8V 6), and saddle shape cluster [Ni(m-bitmb) 4] 2+, has been synthesized. Compound 1 is also demonstrated to be a high activity for benzaldehyde in the oxidation of styrene.

AB - An organic-inorganic hybrid solid material, [Ni(m-bitmb) 4][H 5PMo VI 8V IV 4O 40(V IVO) 2]·8H 2O (m-bitmb = 1, 3-bis (1-imidazol-1-ylmethyl)-2,4,6-trimethylbenzene) 1, constructed from a bi-capped Keggin structural anion [H 5PMo VI 8V IV 4O 40(V IVO) 2] 2- (abbreviated as PMo 8V 6), and saddle shape cluster [Ni(m-bitmb) 4] 2+, has been synthesized. Compound 1 is also demonstrated to be a high activity for benzaldehyde in the oxidation of styrene.

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U2 - 10.1039/c2ce25419k

DO - 10.1039/c2ce25419k

M3 - 文章

AN - SCOPUS:84863895013

SN - 1466-8033

VL - 14

SP - 5148

EP - 5150

JO - CrystEngComm

JF - CrystEngComm

IS - 16

ER -

[H ₅PMo ^VI ₈V ^IV ₄O ₄₀(V ^IVO) ₂]·8H ₂O: Confinement of heteropoly anions in Ni-containing rigid concave surfaces with high catalytic activity in the oxidation of styrene

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