[H 5PMo VI 8V IV 4O 40(V IVO) 2]·8H 2O: Confinement of heteropoly anions in Ni-containing rigid concave surfaces with high catalytic activity in the oxidation of styrene

Jie Fu; Haixia Sun; Yan Xu; Congling Wang; Dunru Zhu; Qi Sun; Hongke Liu

doi:10.1039/c2ce25419k

[H ₅PMo ^VI ₈V ^IV ₄O ₄₀(V ^IVO) ₂]·8H ₂O: Confinement of heteropoly anions in Ni-containing rigid concave surfaces with high catalytic activity in the oxidation of styrene

Jie Fu, Haixia Sun, Yan Xu, Congling Wang, Dunru Zhu, Qi Sun, Hongke Liu

化工学院

科研成果: 期刊稿件 › 文章 › 同行评审

23 引用（Scopus）

摘要

An organic-inorganic hybrid solid material, [Ni(m-bitmb) ₄][H ₅PMo ^VI ₈V ^IV ₄O ₄₀(V ^IVO) ₂]·8H ₂O (m-bitmb = 1, 3-bis (1-imidazol-1-ylmethyl)-2,4,6-trimethylbenzene) 1, constructed from a bi-capped Keggin structural anion [H ₅PMo ^VI ₈V ^IV ₄O ₄₀(V ^IVO) ₂] ^2- (abbreviated as PMo ₈V ₆), and saddle shape cluster [Ni(m-bitmb) ₄] ²⁺, has been synthesized. Compound 1 is also demonstrated to be a high activity for benzaldehyde in the oxidation of styrene.

源语言	英语
页（从-至）	5148-5150
页数	3
期刊	CrystEngComm
卷	14
期	16
DOI	https://doi.org/10.1039/c2ce25419k
出版状态	已出版 - 21 8月 2012

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10.1039/c2ce25419k

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title = "[H 5PMo VI 8V IV 4O 40(V IVO) 2]·8H 2O: Confinement of heteropoly anions in Ni-containing rigid concave surfaces with high catalytic activity in the oxidation of styrene",

abstract = "An organic-inorganic hybrid solid material, [Ni(m-bitmb) 4][H 5PMo VI 8V IV 4O 40(V IVO) 2]·8H 2O (m-bitmb = 1, 3-bis (1-imidazol-1-ylmethyl)-2,4,6-trimethylbenzene) 1, constructed from a bi-capped Keggin structural anion [H 5PMo VI 8V IV 4O 40(V IVO) 2] 2- (abbreviated as PMo 8V 6), and saddle shape cluster [Ni(m-bitmb) 4] 2+, has been synthesized. Compound 1 is also demonstrated to be a high activity for benzaldehyde in the oxidation of styrene.",

author = "Jie Fu and Haixia Sun and Yan Xu and Congling Wang and Dunru Zhu and Qi Sun and Hongke Liu",

year = "2012",

month = aug,

day = "21",

doi = "10.1039/c2ce25419k",

language = "英语",

volume = "14",

pages = "5148--5150",

journal = "CrystEngComm",

issn = "1466-8033",

publisher = "Royal Society of Chemistry",

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TY - JOUR

T1 - [H 5PMo VI 8V IV 4O 40(V IVO) 2]·8H 2O

T2 - Confinement of heteropoly anions in Ni-containing rigid concave surfaces with high catalytic activity in the oxidation of styrene

AU - Fu, Jie

AU - Sun, Haixia

AU - Xu, Yan

AU - Wang, Congling

AU - Zhu, Dunru

AU - Sun, Qi

AU - Liu, Hongke

PY - 2012/8/21

Y1 - 2012/8/21

N2 - An organic-inorganic hybrid solid material, [Ni(m-bitmb) 4][H 5PMo VI 8V IV 4O 40(V IVO) 2]·8H 2O (m-bitmb = 1, 3-bis (1-imidazol-1-ylmethyl)-2,4,6-trimethylbenzene) 1, constructed from a bi-capped Keggin structural anion [H 5PMo VI 8V IV 4O 40(V IVO) 2] 2- (abbreviated as PMo 8V 6), and saddle shape cluster [Ni(m-bitmb) 4] 2+, has been synthesized. Compound 1 is also demonstrated to be a high activity for benzaldehyde in the oxidation of styrene.

AB - An organic-inorganic hybrid solid material, [Ni(m-bitmb) 4][H 5PMo VI 8V IV 4O 40(V IVO) 2]·8H 2O (m-bitmb = 1, 3-bis (1-imidazol-1-ylmethyl)-2,4,6-trimethylbenzene) 1, constructed from a bi-capped Keggin structural anion [H 5PMo VI 8V IV 4O 40(V IVO) 2] 2- (abbreviated as PMo 8V 6), and saddle shape cluster [Ni(m-bitmb) 4] 2+, has been synthesized. Compound 1 is also demonstrated to be a high activity for benzaldehyde in the oxidation of styrene.

UR - http://www.scopus.com/inward/record.url?scp=84863895013&partnerID=8YFLogxK

U2 - 10.1039/c2ce25419k

DO - 10.1039/c2ce25419k

M3 - 文章

AN - SCOPUS:84863895013

SN - 1466-8033

VL - 14

SP - 5148

EP - 5150

JO - CrystEngComm

JF - CrystEngComm

IS - 16

ER -

[H 5PMo VI 8V IV 4O 40(V IVO) 2]·8H 2O: Confinement of heteropoly anions in Ni-containing rigid concave surfaces with high catalytic activity in the oxidation of styrene

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[H ₅PMo ^VI ₈V ^IV ₄O ₄₀(V ^IVO) ₂]·8H ₂O: Confinement of heteropoly anions in Ni-containing rigid concave surfaces with high catalytic activity in the oxidation of styrene