Highly enantioselective allylation of aldehydes catalyzed by indium(III) - PYBOX complex

Jun Lu; Shun Jun Ji; Yong Chua Teo; Teck Peng Loh

doi:10.1021/ol047711c

Highly enantioselective allylation of aldehydes catalyzed by indium(III) - PYBOX complex

Jun Lu, Shun Jun Ji, Yong Chua Teo, Teck Peng Loh

Research output: Contribution to journal › Article › peer-review

79 Scopus citations

Abstract

(Chemical Equation Presented) A chiral indium(III) - PYBOX complex prepared from indium triflate and chiral PYBOX has been discovered to effect high enantioselectivities in the addition of allyltributyl stannane to aldehydes. The allylation of a variety of aromatic, α,β-unsaturated, and aliphatic aldehydes resulted in good yields and high enantioselectivities (up to 94% ee).

Original language	English
Pages (from-to)	159-161
Number of pages	3
Journal	Organic Letters
Volume	7
Issue number	1
DOIs	https://doi.org/10.1021/ol047711c
State	Published - 6 Jan 2005
Externally published	Yes

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10.1021/ol047711c

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title = "Highly enantioselective allylation of aldehydes catalyzed by indium(III) - PYBOX complex",

abstract = "(Chemical Equation Presented) A chiral indium(III) - PYBOX complex prepared from indium triflate and chiral PYBOX has been discovered to effect high enantioselectivities in the addition of allyltributyl stannane to aldehydes. The allylation of a variety of aromatic, α,β-unsaturated, and aliphatic aldehydes resulted in good yields and high enantioselectivities (up to 94% ee).",

author = "Jun Lu and Ji, {Shun Jun} and Teo, {Yong Chua} and Loh, {Teck Peng}",

year = "2005",

month = jan,

day = "6",

doi = "10.1021/ol047711c",

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pages = "159--161",

journal = "Organic Letters",

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T1 - Highly enantioselective allylation of aldehydes catalyzed by indium(III) - PYBOX complex

AU - Lu, Jun

AU - Ji, Shun Jun

AU - Teo, Yong Chua

AU - Loh, Teck Peng

PY - 2005/1/6

Y1 - 2005/1/6

N2 - (Chemical Equation Presented) A chiral indium(III) - PYBOX complex prepared from indium triflate and chiral PYBOX has been discovered to effect high enantioselectivities in the addition of allyltributyl stannane to aldehydes. The allylation of a variety of aromatic, α,β-unsaturated, and aliphatic aldehydes resulted in good yields and high enantioselectivities (up to 94% ee).

AB - (Chemical Equation Presented) A chiral indium(III) - PYBOX complex prepared from indium triflate and chiral PYBOX has been discovered to effect high enantioselectivities in the addition of allyltributyl stannane to aldehydes. The allylation of a variety of aromatic, α,β-unsaturated, and aliphatic aldehydes resulted in good yields and high enantioselectivities (up to 94% ee).

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U2 - 10.1021/ol047711c

DO - 10.1021/ol047711c

M3 - 文章

C2 - 15625002

AN - SCOPUS:12344274699

SN - 1523-7060

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SP - 159

EP - 161

JO - Organic Letters

JF - Organic Letters

IS - 1

ER -

Highly enantioselective allylation of aldehydes catalyzed by indium(III) - PYBOX complex

Abstract

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