Highly enantioselective allylation of aldehydes catalyzed by indium(III) - PYBOX complex

Jun Lu; Shun Jun Ji; Yong Chua Teo; Teck Peng Loh

doi:10.1021/ol047711c

Highly enantioselective allylation of aldehydes catalyzed by indium(III) - PYBOX complex

Jun Lu, Shun Jun Ji, Yong Chua Teo, Teck Peng Loh

科研成果: 期刊稿件 › 文章 › 同行评审

79 引用（Scopus）

摘要

(Chemical Equation Presented) A chiral indium(III) - PYBOX complex prepared from indium triflate and chiral PYBOX has been discovered to effect high enantioselectivities in the addition of allyltributyl stannane to aldehydes. The allylation of a variety of aromatic, α,β-unsaturated, and aliphatic aldehydes resulted in good yields and high enantioselectivities (up to 94% ee).

源语言	英语
页（从-至）	159-161
页数	3
期刊	Organic Letters
卷	7
期	1
DOI	https://doi.org/10.1021/ol047711c
出版状态	已出版 - 6 1月 2005
已对外发布	是

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10.1021/ol047711c

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abstract = "(Chemical Equation Presented) A chiral indium(III) - PYBOX complex prepared from indium triflate and chiral PYBOX has been discovered to effect high enantioselectivities in the addition of allyltributyl stannane to aldehydes. The allylation of a variety of aromatic, α,β-unsaturated, and aliphatic aldehydes resulted in good yields and high enantioselectivities (up to 94% ee).",

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AU - Ji, Shun Jun

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AU - Loh, Teck Peng

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AB - (Chemical Equation Presented) A chiral indium(III) - PYBOX complex prepared from indium triflate and chiral PYBOX has been discovered to effect high enantioselectivities in the addition of allyltributyl stannane to aldehydes. The allylation of a variety of aromatic, α,β-unsaturated, and aliphatic aldehydes resulted in good yields and high enantioselectivities (up to 94% ee).

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Highly enantioselective allylation of aldehydes catalyzed by indium(III) - PYBOX complex

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