HP(O)Ph2/H2O-promoted hydrodefluorination of trifluoromethyl alkenes

Xue Qiang Chu; Li Wen Sun; Yu Lan Chen; Jia Wei Chen; Xuan Ying; Mengtao Ma; Zhi Liang Shen

doi:10.1039/d1gc04645d

HP(O)Ph₂/H₂O-promoted hydrodefluorination of trifluoromethyl alkenes

Xue Qiang Chu, Li Wen Sun, Yu Lan Chen, Jia Wei Chen, Xuan Ying, Mengtao Ma, Zhi Liang Shen

School of Chemistry and Moleculai Engineering

Research output: Contribution to journal › Article › peer-review

28 Scopus citations

Abstract

An efficient transition-metal-free hydrodefluorination reaction of trifluoromethyl alkenes for accessing gem-difluoroalkenes is developed. It was surprising to find that the phosphoryl anion is able to mediate the defluorination. The successful realization of the reaction could also be attributed to the utility of water as an eco-friendly promoter.

Original language	English
Pages (from-to)	2777-2782
Number of pages	6
Journal	Green Chemistry
Volume	24
Issue number	7
DOIs	https://doi.org/10.1039/d1gc04645d
State	Published - 4 Mar 2022

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abstract = "An efficient transition-metal-free hydrodefluorination reaction of trifluoromethyl alkenes for accessing gem-difluoroalkenes is developed. It was surprising to find that the phosphoryl anion is able to mediate the defluorination. The successful realization of the reaction could also be attributed to the utility of water as an eco-friendly promoter.",

author = "Chu, {Xue Qiang} and Sun, {Li Wen} and Chen, {Yu Lan} and Chen, {Jia Wei} and Xuan Ying and Mengtao Ma and Shen, {Zhi Liang}",

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AU - Chu, Xue Qiang

AU - Sun, Li Wen

AU - Chen, Yu Lan

AU - Chen, Jia Wei

AU - Ying, Xuan

AU - Ma, Mengtao

AU - Shen, Zhi Liang

PY - 2022/3/4

Y1 - 2022/3/4

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AB - An efficient transition-metal-free hydrodefluorination reaction of trifluoromethyl alkenes for accessing gem-difluoroalkenes is developed. It was surprising to find that the phosphoryl anion is able to mediate the defluorination. The successful realization of the reaction could also be attributed to the utility of water as an eco-friendly promoter.

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JO - Green Chemistry

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ER -

HP(O)Ph₂/H₂O-promoted hydrodefluorination of trifluoromethyl alkenes

Abstract

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