HP(O)Ph2/H2O-promoted hydrodefluorination of trifluoromethyl alkenes

Xue Qiang Chu, Li Wen Sun, Yu Lan Chen, Jia Wei Chen, Xuan Ying, Mengtao Ma, Zhi Liang Shen

科研成果: 期刊稿件文章同行评审

28 引用 (Scopus)

摘要

An efficient transition-metal-free hydrodefluorination reaction of trifluoromethyl alkenes for accessing gem-difluoroalkenes is developed. It was surprising to find that the phosphoryl anion is able to mediate the defluorination. The successful realization of the reaction could also be attributed to the utility of water as an eco-friendly promoter.

源语言英语
页(从-至)2777-2782
页数6
期刊Green Chemistry
24
7
DOI
出版状态已出版 - 4 3月 2022

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