Molecular and crystal structure of [NO2Py]2[Ni(mnt)2] (NO2Py = 1-(4-nitrobenzyl)pyridinium, mnt2- = maleonitriledithiolate)

Ren Xiaoming; Xu Yan; Meng Qingjin; Hu Chuanjiang; Lu Changsheng; Wang Huaqing

doi:10.1023/A:1009509427097

Molecular and crystal structure of [NO₂Py]₂[Ni(mnt)₂] (NO₂Py = 1-(4-nitrobenzyl)pyridinium, mnt^2- = maleonitriledithiolate)

Ren Xiaoming, Xu Yan, Meng Qingjin, Hu Chuanjiang, Lu Changsheng, Wang Huaqing

Nanjing University

Research output: Contribution to journal › Article › peer-review

Abstract

The structure of [NO₂Py]₂[Ni(mnt)₂], as determined by x-ray single crystal analysis, consists of two 1-(4-nitrobenzyl)pyridinium cations and one [Ni(mnt)₂]^2- anion. The crystallographic data for the complex:monoclinic P2₁/n, a = 9.913(2) Å, b = 11.968(2) Å, c = 14.566(3) Å, β = 100.36(3)°, V = 1699.9(6) Å³, Z = 2. The [Ni(mnt)₂]^2- anion has a crystallographically imposed center of symmetry and exhibits a relatively planar structure. The cation, [NO₂Py]⁺, adopts a conformation where both the aromatic rings are twisted to the C11-C10-N3 reference plane. The anions (A) and the cations (C) consist of alternating layers (i.e., of type ⋯C₁A₁C₂A₂C₁A₁C₂⋯) along the c axis of the crystallographic unit cell.

Original language	English
Pages (from-to)	91-94
Number of pages	4
Journal	Journal of Chemical Crystallography
Volume	30
Issue number	2
DOIs	https://doi.org/10.1023/A:1009509427097
State	Published - Feb 2000
Externally published	Yes

Keywords

1-(4-nitrobenzyl)pyridinium
Bis(maleonitriledithiolato)nickelate(II) complex
X-ray structure

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title = "Molecular and crystal structure of [NO2Py]2[Ni(mnt)2] (NO2Py = 1-(4-nitrobenzyl)pyridinium, mnt2- = maleonitriledithiolate)",

abstract = "The structure of [NO2Py]2[Ni(mnt)2], as determined by x-ray single crystal analysis, consists of two 1-(4-nitrobenzyl)pyridinium cations and one [Ni(mnt)2]2- anion. The crystallographic data for the complex:monoclinic P21/n, a = 9.913(2) {\AA}, b = 11.968(2) {\AA}, c = 14.566(3) {\AA}, β = 100.36(3)°, V = 1699.9(6) {\AA}3, Z = 2. The [Ni(mnt)2]2- anion has a crystallographically imposed center of symmetry and exhibits a relatively planar structure. The cation, [NO2Py]+, adopts a conformation where both the aromatic rings are twisted to the C11-C10-N3 reference plane. The anions (A) and the cations (C) consist of alternating layers (i.e., of type ⋯C1A1C2A2C1A1 C2⋯) along the c axis of the crystallographic unit cell.",

keywords = "1-(4-nitrobenzyl)pyridinium, Bis(maleonitriledithiolato)nickelate(II) complex, X-ray structure",

author = "Ren Xiaoming and Xu Yan and Meng Qingjin and Hu Chuanjiang and Lu Changsheng and Wang Huaqing",

year = "2000",

month = feb,

doi = "10.1023/A:1009509427097",

language = "英语",

volume = "30",

pages = "91--94",

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TY - JOUR

T1 - Molecular and crystal structure of [NO2Py]2[Ni(mnt)2] (NO2Py = 1-(4-nitrobenzyl)pyridinium, mnt2- = maleonitriledithiolate)

AU - Xiaoming, Ren

AU - Yan, Xu

AU - Qingjin, Meng

AU - Chuanjiang, Hu

AU - Changsheng, Lu

AU - Huaqing, Wang

PY - 2000/2

Y1 - 2000/2

N2 - The structure of [NO2Py]2[Ni(mnt)2], as determined by x-ray single crystal analysis, consists of two 1-(4-nitrobenzyl)pyridinium cations and one [Ni(mnt)2]2- anion. The crystallographic data for the complex:monoclinic P21/n, a = 9.913(2) Å, b = 11.968(2) Å, c = 14.566(3) Å, β = 100.36(3)°, V = 1699.9(6) Å3, Z = 2. The [Ni(mnt)2]2- anion has a crystallographically imposed center of symmetry and exhibits a relatively planar structure. The cation, [NO2Py]+, adopts a conformation where both the aromatic rings are twisted to the C11-C10-N3 reference plane. The anions (A) and the cations (C) consist of alternating layers (i.e., of type ⋯C1A1C2A2C1A1 C2⋯) along the c axis of the crystallographic unit cell.

AB - The structure of [NO2Py]2[Ni(mnt)2], as determined by x-ray single crystal analysis, consists of two 1-(4-nitrobenzyl)pyridinium cations and one [Ni(mnt)2]2- anion. The crystallographic data for the complex:monoclinic P21/n, a = 9.913(2) Å, b = 11.968(2) Å, c = 14.566(3) Å, β = 100.36(3)°, V = 1699.9(6) Å3, Z = 2. The [Ni(mnt)2]2- anion has a crystallographically imposed center of symmetry and exhibits a relatively planar structure. The cation, [NO2Py]+, adopts a conformation where both the aromatic rings are twisted to the C11-C10-N3 reference plane. The anions (A) and the cations (C) consist of alternating layers (i.e., of type ⋯C1A1C2A2C1A1 C2⋯) along the c axis of the crystallographic unit cell.

KW - 1-(4-nitrobenzyl)pyridinium

KW - Bis(maleonitriledithiolato)nickelate(II) complex

KW - X-ray structure

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DO - 10.1023/A:1009509427097

M3 - 文章

AN - SCOPUS:0034343066

SN - 1074-1542

VL - 30

SP - 91

EP - 94

JO - Journal of Chemical Crystallography

JF - Journal of Chemical Crystallography

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ER -

Molecular and crystal structure of [NO₂Py]₂[Ni(mnt)₂] (NO₂Py = 1-(4-nitrobenzyl)pyridinium, mnt^2- = maleonitriledithiolate)

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