TY - JOUR
T1 - Molecular and crystal structure of [NO2Py]2[Ni(mnt)2] (NO2Py = 1-(4-nitrobenzyl)pyridinium, mnt2- = maleonitriledithiolate)
AU - Xiaoming, Ren
AU - Yan, Xu
AU - Qingjin, Meng
AU - Chuanjiang, Hu
AU - Changsheng, Lu
AU - Huaqing, Wang
PY - 2000/2
Y1 - 2000/2
N2 - The structure of [NO2Py]2[Ni(mnt)2], as determined by x-ray single crystal analysis, consists of two 1-(4-nitrobenzyl)pyridinium cations and one [Ni(mnt)2]2- anion. The crystallographic data for the complex:monoclinic P21/n, a = 9.913(2) Å, b = 11.968(2) Å, c = 14.566(3) Å, β = 100.36(3)°, V = 1699.9(6) Å3, Z = 2. The [Ni(mnt)2]2- anion has a crystallographically imposed center of symmetry and exhibits a relatively planar structure. The cation, [NO2Py]+, adopts a conformation where both the aromatic rings are twisted to the C11-C10-N3 reference plane. The anions (A) and the cations (C) consist of alternating layers (i.e., of type ⋯C1A1C2A2C1A1 C2⋯) along the c axis of the crystallographic unit cell.
AB - The structure of [NO2Py]2[Ni(mnt)2], as determined by x-ray single crystal analysis, consists of two 1-(4-nitrobenzyl)pyridinium cations and one [Ni(mnt)2]2- anion. The crystallographic data for the complex:monoclinic P21/n, a = 9.913(2) Å, b = 11.968(2) Å, c = 14.566(3) Å, β = 100.36(3)°, V = 1699.9(6) Å3, Z = 2. The [Ni(mnt)2]2- anion has a crystallographically imposed center of symmetry and exhibits a relatively planar structure. The cation, [NO2Py]+, adopts a conformation where both the aromatic rings are twisted to the C11-C10-N3 reference plane. The anions (A) and the cations (C) consist of alternating layers (i.e., of type ⋯C1A1C2A2C1A1 C2⋯) along the c axis of the crystallographic unit cell.
KW - 1-(4-nitrobenzyl)pyridinium
KW - Bis(maleonitriledithiolato)nickelate(II) complex
KW - X-ray structure
UR - http://www.scopus.com/inward/record.url?scp=0034343066&partnerID=8YFLogxK
U2 - 10.1023/A:1009509427097
DO - 10.1023/A:1009509427097
M3 - 文章
AN - SCOPUS:0034343066
SN - 1074-1542
VL - 30
SP - 91
EP - 94
JO - Journal of Chemical Crystallography
JF - Journal of Chemical Crystallography
IS - 2
ER -