Palladium-catalyzed silylation reaction between benzylic halides and silylboronate

Zhi Dao Huang; Ran Ding; Peng Wang; Yun He Xu; Teck Peng Loh

doi:10.1039/c6cc00713a

Palladium-catalyzed silylation reaction between benzylic halides and silylboronate

Zhi Dao Huang, Ran Ding, Peng Wang, Yun He Xu, Teck Peng Loh

Research output: Contribution to journal › Article › peer-review

35 Scopus citations

Abstract

An efficient Pd-catalyzed silylation reaction of benzylic halides with silylboronate is reported. In this reaction, primary and secondary benzylic halides could react well with silylboronates to afford benzylic silanes. This reaction accommodates a broad substrate scope and proceeds smoothly under very mild reaction conditions. The corresponding products could be obtained in moderate to high yields and with stereospecificity.

Original language	English
Pages (from-to)	5609-5612
Number of pages	4
Journal	Chemical Communications
Volume	52
Issue number	32
DOIs	https://doi.org/10.1039/c6cc00713a
State	Published - 25 Apr 2016
Externally published	Yes

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title = "Palladium-catalyzed silylation reaction between benzylic halides and silylboronate",

abstract = "An efficient Pd-catalyzed silylation reaction of benzylic halides with silylboronate is reported. In this reaction, primary and secondary benzylic halides could react well with silylboronates to afford benzylic silanes. This reaction accommodates a broad substrate scope and proceeds smoothly under very mild reaction conditions. The corresponding products could be obtained in moderate to high yields and with stereospecificity.",

author = "Huang, {Zhi Dao} and Ran Ding and Peng Wang and Xu, {Yun He} and Loh, {Teck Peng}",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2016.",

year = "2016",

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T1 - Palladium-catalyzed silylation reaction between benzylic halides and silylboronate

AU - Huang, Zhi Dao

AU - Ding, Ran

AU - Wang, Peng

AU - Xu, Yun He

AU - Loh, Teck Peng

PY - 2016/4/25

Y1 - 2016/4/25

N2 - An efficient Pd-catalyzed silylation reaction of benzylic halides with silylboronate is reported. In this reaction, primary and secondary benzylic halides could react well with silylboronates to afford benzylic silanes. This reaction accommodates a broad substrate scope and proceeds smoothly under very mild reaction conditions. The corresponding products could be obtained in moderate to high yields and with stereospecificity.

AB - An efficient Pd-catalyzed silylation reaction of benzylic halides with silylboronate is reported. In this reaction, primary and secondary benzylic halides could react well with silylboronates to afford benzylic silanes. This reaction accommodates a broad substrate scope and proceeds smoothly under very mild reaction conditions. The corresponding products could be obtained in moderate to high yields and with stereospecificity.

UR - http://www.scopus.com/inward/record.url?scp=84964613564&partnerID=8YFLogxK

U2 - 10.1039/c6cc00713a

DO - 10.1039/c6cc00713a

M3 - 文章

AN - SCOPUS:84964613564

SN - 1359-7345

VL - 52

SP - 5609

EP - 5612

JO - Chemical Communications

JF - Chemical Communications

IS - 32

ER -

Palladium-catalyzed silylation reaction between benzylic halides and silylboronate

Abstract

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