Palladium-catalyzed silylation reaction between benzylic halides and silylboronate

Zhi Dao Huang; Ran Ding; Peng Wang; Yun He Xu; Teck Peng Loh

doi:10.1039/c6cc00713a

Palladium-catalyzed silylation reaction between benzylic halides and silylboronate

Zhi Dao Huang, Ran Ding, Peng Wang, Yun He Xu, Teck Peng Loh

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35 引用（Scopus）

摘要

An efficient Pd-catalyzed silylation reaction of benzylic halides with silylboronate is reported. In this reaction, primary and secondary benzylic halides could react well with silylboronates to afford benzylic silanes. This reaction accommodates a broad substrate scope and proceeds smoothly under very mild reaction conditions. The corresponding products could be obtained in moderate to high yields and with stereospecificity.

源语言	英语
页（从-至）	5609-5612
页数	4
期刊	Chemical Communications
卷	52
期	32
DOI	https://doi.org/10.1039/c6cc00713a
出版状态	已出版 - 25 4月 2016
已对外发布	是

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abstract = "An efficient Pd-catalyzed silylation reaction of benzylic halides with silylboronate is reported. In this reaction, primary and secondary benzylic halides could react well with silylboronates to afford benzylic silanes. This reaction accommodates a broad substrate scope and proceeds smoothly under very mild reaction conditions. The corresponding products could be obtained in moderate to high yields and with stereospecificity.",

author = "Huang, {Zhi Dao} and Ran Ding and Peng Wang and Xu, {Yun He} and Loh, {Teck Peng}",

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AU - Huang, Zhi Dao

AU - Ding, Ran

AU - Wang, Peng

AU - Xu, Yun He

AU - Loh, Teck Peng

PY - 2016/4/25

Y1 - 2016/4/25

N2 - An efficient Pd-catalyzed silylation reaction of benzylic halides with silylboronate is reported. In this reaction, primary and secondary benzylic halides could react well with silylboronates to afford benzylic silanes. This reaction accommodates a broad substrate scope and proceeds smoothly under very mild reaction conditions. The corresponding products could be obtained in moderate to high yields and with stereospecificity.

AB - An efficient Pd-catalyzed silylation reaction of benzylic halides with silylboronate is reported. In this reaction, primary and secondary benzylic halides could react well with silylboronates to afford benzylic silanes. This reaction accommodates a broad substrate scope and proceeds smoothly under very mild reaction conditions. The corresponding products could be obtained in moderate to high yields and with stereospecificity.

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DO - 10.1039/c6cc00713a

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JO - Chemical Communications

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Palladium-catalyzed silylation reaction between benzylic halides and silylboronate

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