Photoinduced Cu(II)-mediated RDRP to P(VDF-co-CTFE)-g-PAN

Xin Hu; Guopeng Cui; Ning Zhu; Jinglin Zhai; Kai Guo

doi:10.3390/polym10010068

Photoinduced Cu(II)-mediated RDRP to P(VDF-co-CTFE)-g-PAN

Xin Hu, Guopeng Cui, Ning Zhu, Jinglin Zhai, Kai Guo

COLLEGE OF BIOTECHNOLOGY AND PHARMACEUTICAL ENGINEERING

Nanjing Tech University

Research output: Contribution to journal › Article › peer-review

14 Scopus citations

Abstract

Photoinduced Cu(II)-mediated reversible deactivation radical polymerization (RDRP) was employed to synthesize poly(vinylidene fluoride-co-chlorotrifluoroethylene)-graft-polyacrylonitrile (P(VDF-co-CTFE)-g-PAN). The concentration of copper catalyst (CuCl₂) loading was as low as 1/64 equivalent to chlorine atom in the presence of Me₆-Tren under UV irradiation. The light-responsive nature of graft polymerization was confirmed by "off-on" impulsive irradiation experiments. Temporal control of the polymerization process and varied graft contents were achieved via this photoinduced Cu(II)-mediated RDRP.

Original language	English
Article number	68
Journal	Polymers
Volume	10
Issue number	1
DOIs	https://doi.org/10.3390/polym10010068
State	Published - 13 Jan 2018

Keywords

Copper-mediated RDRP
Fluoropolymer
Graft
PAN
Photoinduced

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abstract = "Photoinduced Cu(II)-mediated reversible deactivation radical polymerization (RDRP) was employed to synthesize poly(vinylidene fluoride-co-chlorotrifluoroethylene)-graft-polyacrylonitrile (P(VDF-co-CTFE)-g-PAN). The concentration of copper catalyst (CuCl2) loading was as low as 1/64 equivalent to chlorine atom in the presence of Me6-Tren under UV irradiation. The light-responsive nature of graft polymerization was confirmed by {"}off-on{"} impulsive irradiation experiments. Temporal control of the polymerization process and varied graft contents were achieved via this photoinduced Cu(II)-mediated RDRP.",

keywords = "Copper-mediated RDRP, Fluoropolymer, Graft, PAN, Photoinduced",

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doi = "10.3390/polym10010068",

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T1 - Photoinduced Cu(II)-mediated RDRP to P(VDF-co-CTFE)-g-PAN

AU - Hu, Xin

AU - Cui, Guopeng

AU - Zhu, Ning

AU - Zhai, Jinglin

AU - Guo, Kai

PY - 2018/1/13

Y1 - 2018/1/13

N2 - Photoinduced Cu(II)-mediated reversible deactivation radical polymerization (RDRP) was employed to synthesize poly(vinylidene fluoride-co-chlorotrifluoroethylene)-graft-polyacrylonitrile (P(VDF-co-CTFE)-g-PAN). The concentration of copper catalyst (CuCl2) loading was as low as 1/64 equivalent to chlorine atom in the presence of Me6-Tren under UV irradiation. The light-responsive nature of graft polymerization was confirmed by "off-on" impulsive irradiation experiments. Temporal control of the polymerization process and varied graft contents were achieved via this photoinduced Cu(II)-mediated RDRP.

AB - Photoinduced Cu(II)-mediated reversible deactivation radical polymerization (RDRP) was employed to synthesize poly(vinylidene fluoride-co-chlorotrifluoroethylene)-graft-polyacrylonitrile (P(VDF-co-CTFE)-g-PAN). The concentration of copper catalyst (CuCl2) loading was as low as 1/64 equivalent to chlorine atom in the presence of Me6-Tren under UV irradiation. The light-responsive nature of graft polymerization was confirmed by "off-on" impulsive irradiation experiments. Temporal control of the polymerization process and varied graft contents were achieved via this photoinduced Cu(II)-mediated RDRP.

KW - Copper-mediated RDRP

KW - Fluoropolymer

KW - Graft

KW - PAN

KW - Photoinduced

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U2 - 10.3390/polym10010068

DO - 10.3390/polym10010068

M3 - 文章

AN - SCOPUS:85040784018

SN - 2073-4360

VL - 10

JO - Polymers

JF - Polymers

IS - 1

M1 - 68

ER -

Photoinduced Cu(II)-mediated RDRP to P(VDF-co-CTFE)-g-PAN

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Keywords

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