Photoinduced Cu(II)-mediated RDRP to P(VDF-co-CTFE)-g-PAN

Xin Hu; Guopeng Cui; Ning Zhu; Jinglin Zhai; Kai Guo

doi:10.3390/polym10010068

Photoinduced Cu(II)-mediated RDRP to P(VDF-co-CTFE)-g-PAN

Xin Hu, Guopeng Cui, Ning Zhu, Jinglin Zhai, Kai Guo

生物与制药工程学院

Nanjing Tech University

科研成果: 期刊稿件 › 文章 › 同行评审

14 引用（Scopus）

摘要

Photoinduced Cu(II)-mediated reversible deactivation radical polymerization (RDRP) was employed to synthesize poly(vinylidene fluoride-co-chlorotrifluoroethylene)-graft-polyacrylonitrile (P(VDF-co-CTFE)-g-PAN). The concentration of copper catalyst (CuCl₂) loading was as low as 1/64 equivalent to chlorine atom in the presence of Me₆-Tren under UV irradiation. The light-responsive nature of graft polymerization was confirmed by "off-on" impulsive irradiation experiments. Temporal control of the polymerization process and varied graft contents were achieved via this photoinduced Cu(II)-mediated RDRP.

源语言	英语
文章编号	68
期刊	Polymers
卷	10
期	1
DOI	https://doi.org/10.3390/polym10010068
出版状态	已出版 - 13 1月 2018

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abstract = "Photoinduced Cu(II)-mediated reversible deactivation radical polymerization (RDRP) was employed to synthesize poly(vinylidene fluoride-co-chlorotrifluoroethylene)-graft-polyacrylonitrile (P(VDF-co-CTFE)-g-PAN). The concentration of copper catalyst (CuCl2) loading was as low as 1/64 equivalent to chlorine atom in the presence of Me6-Tren under UV irradiation. The light-responsive nature of graft polymerization was confirmed by {"}off-on{"} impulsive irradiation experiments. Temporal control of the polymerization process and varied graft contents were achieved via this photoinduced Cu(II)-mediated RDRP.",

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author = "Xin Hu and Guopeng Cui and Ning Zhu and Jinglin Zhai and Kai Guo",

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T1 - Photoinduced Cu(II)-mediated RDRP to P(VDF-co-CTFE)-g-PAN

AU - Hu, Xin

AU - Cui, Guopeng

AU - Zhu, Ning

AU - Zhai, Jinglin

AU - Guo, Kai

PY - 2018/1/13

Y1 - 2018/1/13

N2 - Photoinduced Cu(II)-mediated reversible deactivation radical polymerization (RDRP) was employed to synthesize poly(vinylidene fluoride-co-chlorotrifluoroethylene)-graft-polyacrylonitrile (P(VDF-co-CTFE)-g-PAN). The concentration of copper catalyst (CuCl2) loading was as low as 1/64 equivalent to chlorine atom in the presence of Me6-Tren under UV irradiation. The light-responsive nature of graft polymerization was confirmed by "off-on" impulsive irradiation experiments. Temporal control of the polymerization process and varied graft contents were achieved via this photoinduced Cu(II)-mediated RDRP.

AB - Photoinduced Cu(II)-mediated reversible deactivation radical polymerization (RDRP) was employed to synthesize poly(vinylidene fluoride-co-chlorotrifluoroethylene)-graft-polyacrylonitrile (P(VDF-co-CTFE)-g-PAN). The concentration of copper catalyst (CuCl2) loading was as low as 1/64 equivalent to chlorine atom in the presence of Me6-Tren under UV irradiation. The light-responsive nature of graft polymerization was confirmed by "off-on" impulsive irradiation experiments. Temporal control of the polymerization process and varied graft contents were achieved via this photoinduced Cu(II)-mediated RDRP.

KW - Copper-mediated RDRP

KW - Fluoropolymer

KW - Graft

KW - PAN

KW - Photoinduced

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JO - Polymers

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Photoinduced Cu(II)-mediated RDRP to P(VDF-co-CTFE)-g-PAN

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