Readily processed multifunctional SiC catalytic filter for industrial emissions control

Jiahao Chen, Yongliang Yin, Ze Xian Low, Kai Yuan, Wei Wei, Yiqing Zeng, Zhaoxiang Zhong, Weihong Xing

Research output: Contribution to journalArticlepeer-review

7 Scopus citations

Abstract

One step fabrication of SiC catalytic filter is currently limited by the mismatched calcination temperature between SiC filter (>1700°C) and the catalysts (<800°C), and the difficulty in the chemical immobilization of catalysts. Here, a SrTi1−xCoxO3-SiC (STC-SiC) catalytic filter was directly fabricated from raw SiC grains and STC precursor oxides (SrCO3, TiO2, and Co3O4) via a single-step reactive thermal processing (SRTP) approach, which significantly reduced energy consumption and sintering time over 50%. Acid etching enables the active TiO2 and Co3O4 nanoparticles spontaneously formed on STC catalysts in STC-SiC catalytic filter (STC-SiC-A), which induces the generation of oxygen vacancies and facilitates the adsorption and activation of O2 and NO. The STC-SiC-A catalytic filter exhibits highly competitive NO oxidation of 60% and complete dust interception (100%) at 360°C. This work demonstrates an efficient and rapid processing technique of SiC based catalytic filters, which can also be implemented on other ceramic-based catalytic filters.

Original languageEnglish
Article numbere17954
JournalAIChE Journal
Volume69
Issue number4
DOIs
StatePublished - Apr 2023

Keywords

  • NO oxidation
  • PM filtration
  • SiC catalytic filter
  • acid etching
  • single-step reactive thermal processing

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