摘要
One step fabrication of SiC catalytic filter is currently limited by the mismatched calcination temperature between SiC filter (>1700°C) and the catalysts (<800°C), and the difficulty in the chemical immobilization of catalysts. Here, a SrTi1−xCoxO3-SiC (STC-SiC) catalytic filter was directly fabricated from raw SiC grains and STC precursor oxides (SrCO3, TiO2, and Co3O4) via a single-step reactive thermal processing (SRTP) approach, which significantly reduced energy consumption and sintering time over 50%. Acid etching enables the active TiO2 and Co3O4 nanoparticles spontaneously formed on STC catalysts in STC-SiC catalytic filter (STC-SiC-A), which induces the generation of oxygen vacancies and facilitates the adsorption and activation of O2 and NO. The STC-SiC-A catalytic filter exhibits highly competitive NO oxidation of 60% and complete dust interception (100%) at 360°C. This work demonstrates an efficient and rapid processing technique of SiC based catalytic filters, which can also be implemented on other ceramic-based catalytic filters.
源语言 | 英语 |
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文章编号 | e17954 |
期刊 | AIChE Journal |
卷 | 69 |
期 | 4 |
DOI | |
出版状态 | 已出版 - 4月 2023 |