Reductive-Delay Heck 1,1-Diarylation of Terminal Alkenes

Huihui Shao; Yao Zhao; Shuangqiang Wang; Rizhi Chen; Jianrong Steve Zhou; Xiaojin Wu

doi:10.1021/acs.orglett.2c02416

Reductive-Delay Heck 1,1-Diarylation of Terminal Alkenes

Huihui Shao, Yao Zhao, Shuangqiang Wang, Rizhi Chen, Jianrong Steve Zhou, Xiaojin Wu

College of Chemical Engineering

Research output: Contribution to journal › Article › peer-review

13 Scopus citations

Abstract

Pd-catalyzed chemo- and regiocontrollable 1,1-diarylation of unactivated aliphatic alkenes with two aryl halides was developed. Under the cationic reductive-delay Heck pathway, the first aryl insertion is followed by β-H elimination, while the second aryl insertion is terminated by C-H bond formation.

Original language	English
Pages (from-to)	6520-6524
Number of pages	5
Journal	Organic Letters
Volume	24
Issue number	36
DOIs	https://doi.org/10.1021/acs.orglett.2c02416
State	Published - 16 Sep 2022

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title = "Reductive-Delay Heck 1,1-Diarylation of Terminal Alkenes",

abstract = "Pd-catalyzed chemo- and regiocontrollable 1,1-diarylation of unactivated aliphatic alkenes with two aryl halides was developed. Under the cationic reductive-delay Heck pathway, the first aryl insertion is followed by β-H elimination, while the second aryl insertion is terminated by C-H bond formation.",

author = "Huihui Shao and Yao Zhao and Shuangqiang Wang and Rizhi Chen and Zhou, {Jianrong Steve} and Xiaojin Wu",

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T1 - Reductive-Delay Heck 1,1-Diarylation of Terminal Alkenes

AU - Shao, Huihui

AU - Zhao, Yao

AU - Wang, Shuangqiang

AU - Chen, Rizhi

AU - Zhou, Jianrong Steve

AU - Wu, Xiaojin

PY - 2022/9/16

Y1 - 2022/9/16

N2 - Pd-catalyzed chemo- and regiocontrollable 1,1-diarylation of unactivated aliphatic alkenes with two aryl halides was developed. Under the cationic reductive-delay Heck pathway, the first aryl insertion is followed by β-H elimination, while the second aryl insertion is terminated by C-H bond formation.

AB - Pd-catalyzed chemo- and regiocontrollable 1,1-diarylation of unactivated aliphatic alkenes with two aryl halides was developed. Under the cationic reductive-delay Heck pathway, the first aryl insertion is followed by β-H elimination, while the second aryl insertion is terminated by C-H bond formation.

UR - http://www.scopus.com/inward/record.url?scp=85138103993&partnerID=8YFLogxK

U2 - 10.1021/acs.orglett.2c02416

DO - 10.1021/acs.orglett.2c02416

M3 - 文章

C2 - 36047988

AN - SCOPUS:85138103993

SN - 1523-7060

VL - 24

SP - 6520

EP - 6524

JO - Organic Letters

JF - Organic Letters

IS - 36

ER -

Reductive-Delay Heck 1,1-Diarylation of Terminal Alkenes

Abstract

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