Reductive-Delay Heck 1,1-Diarylation of Terminal Alkenes

Huihui Shao, Yao Zhao, Shuangqiang Wang, Rizhi Chen, Jianrong Steve Zhou, Xiaojin Wu

科研成果: 期刊稿件文章同行评审

13 引用 (Scopus)

摘要

Pd-catalyzed chemo- and regiocontrollable 1,1-diarylation of unactivated aliphatic alkenes with two aryl halides was developed. Under the cationic reductive-delay Heck pathway, the first aryl insertion is followed by β-H elimination, while the second aryl insertion is terminated by C-H bond formation.

源语言英语
页(从-至)6520-6524
页数5
期刊Organic Letters
24
36
DOI
出版状态已出版 - 16 9月 2022

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