Synthesis of Pd nanoparticles supported on molecular porous materials by using polyoxovanadate-based metal organic polyhedra as reducing agent

Jie Zhou; Zhuxiu Zhang; Jihai Tang; Xu Qiao

doi:10.1016/j.inoche.2020.108028

Synthesis of Pd nanoparticles supported on molecular porous materials by using polyoxovanadate-based metal organic polyhedra as reducing agent

Jie Zhou, Zhuxiu Zhang, Jihai Tang, Xu Qiao

College of Chemical Engineering

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

Thermal treatment of the mechanical mixture of VMOP-12 and PdCl₂ enabled the reduction of Pd^II to Pd⁰ nanoparticles via VMOP-12 without any external reducing agents. The resulting Pd⁰/VMOP-12 exhibited permanent porosities and well-dispersed Pd nanoparticles with average diameter of 10 nm. The improved catalytic activity of Pd⁰/VMOP-12 over palladium black were observed in the context of methanolysis of ammonia borane.

Original language	English
Article number	108028
Journal	Inorganic Chemistry Communications
Volume	118
DOIs	https://doi.org/10.1016/j.inoche.2020.108028
State	Published - Aug 2020

Keywords

Extrinsic porosity
Methanolysis
Molecular porous materials
Pd nanoparticles
VMOPs

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10.1016/j.inoche.2020.108028

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title = "Synthesis of Pd nanoparticles supported on molecular porous materials by using polyoxovanadate-based metal organic polyhedra as reducing agent",

abstract = "Thermal treatment of the mechanical mixture of VMOP-12 and PdCl2 enabled the reduction of PdII to Pd0 nanoparticles via VMOP-12 without any external reducing agents. The resulting Pd0/VMOP-12 exhibited permanent porosities and well-dispersed Pd nanoparticles with average diameter of 10 nm. The improved catalytic activity of Pd0/VMOP-12 over palladium black were observed in the context of methanolysis of ammonia borane.",

keywords = "Extrinsic porosity, Methanolysis, Molecular porous materials, Pd nanoparticles, VMOPs",

author = "Jie Zhou and Zhuxiu Zhang and Jihai Tang and Xu Qiao",

note = "Publisher Copyright: {\textcopyright} 2020",

year = "2020",

month = aug,

doi = "10.1016/j.inoche.2020.108028",

language = "英语",

volume = "118",

journal = "Inorganic Chemistry Communications",

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T1 - Synthesis of Pd nanoparticles supported on molecular porous materials by using polyoxovanadate-based metal organic polyhedra as reducing agent

AU - Zhou, Jie

AU - Zhang, Zhuxiu

AU - Tang, Jihai

AU - Qiao, Xu

PY - 2020/8

Y1 - 2020/8

N2 - Thermal treatment of the mechanical mixture of VMOP-12 and PdCl2 enabled the reduction of PdII to Pd0 nanoparticles via VMOP-12 without any external reducing agents. The resulting Pd0/VMOP-12 exhibited permanent porosities and well-dispersed Pd nanoparticles with average diameter of 10 nm. The improved catalytic activity of Pd0/VMOP-12 over palladium black were observed in the context of methanolysis of ammonia borane.

AB - Thermal treatment of the mechanical mixture of VMOP-12 and PdCl2 enabled the reduction of PdII to Pd0 nanoparticles via VMOP-12 without any external reducing agents. The resulting Pd0/VMOP-12 exhibited permanent porosities and well-dispersed Pd nanoparticles with average diameter of 10 nm. The improved catalytic activity of Pd0/VMOP-12 over palladium black were observed in the context of methanolysis of ammonia borane.

KW - Extrinsic porosity

KW - Methanolysis

KW - Molecular porous materials

KW - Pd nanoparticles

KW - VMOPs

UR - http://www.scopus.com/inward/record.url?scp=85086471676&partnerID=8YFLogxK

U2 - 10.1016/j.inoche.2020.108028

DO - 10.1016/j.inoche.2020.108028

M3 - 文章

AN - SCOPUS:85086471676

SN - 1387-7003

VL - 118

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

M1 - 108028

ER -

Synthesis of Pd nanoparticles supported on molecular porous materials by using polyoxovanadate-based metal organic polyhedra as reducing agent

Abstract

Keywords

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