@article{a3f6dc5e833f4b73b64c33309637dc76,
title = "Synthesis of Pd nanoparticles supported on molecular porous materials by using polyoxovanadate-based metal organic polyhedra as reducing agent",
abstract = "Thermal treatment of the mechanical mixture of VMOP-12 and PdCl2 enabled the reduction of PdII to Pd0 nanoparticles via VMOP-12 without any external reducing agents. The resulting Pd0/VMOP-12 exhibited permanent porosities and well-dispersed Pd nanoparticles with average diameter of 10 nm. The improved catalytic activity of Pd0/VMOP-12 over palladium black were observed in the context of methanolysis of ammonia borane.",
keywords = "Extrinsic porosity, Methanolysis, Molecular porous materials, Pd nanoparticles, VMOPs",
author = "Jie Zhou and Zhuxiu Zhang and Jihai Tang and Xu Qiao",
note = "Publisher Copyright: {\textcopyright} 2020",
year = "2020",
month = aug,
doi = "10.1016/j.inoche.2020.108028",
language = "英语",
volume = "118",
journal = "Inorganic Chemistry Communications",
issn = "1387-7003",
publisher = "Elsevier B.V.",
}