The 1:2 bis(maleonitriledithiolato)-palladium(II) complex of the N-(2-fluoro-4-bromobenzyl)pyridinium cation

Youcun Chen; Jingli Xie; Xiaoming Ren; Guangxiang Liu

doi:10.1107/S1600536803005270

The 1:2 bis(maleonitriledithiolato)-palladium(II) complex of the N-(2-fluoro-4-bromobenzyl)pyridinium cation

Youcun Chen, Jingli Xie, Xiaoming Ren, Guangxiang Liu

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

In the title salt, (C₁₂H₁₀BrFN)₂[Pd(C ₄N₂S₂)₂] or [N-(2-fluoro-4- bromobenzyl)pyridinium]₂[Pd(mnt)₂], where mnt^2- denotes maleonitriledithiolate, the Pd²⁺ ion is coordinated by four S atoms of two mnt^2- ligands in a planar geometry. The asymmetric unit is composed of one N-(2-fluoro-4-bromo-benzyl)pyridinium cation and one-half [Pd(mnt)₂]^2- anion. The adjacent counter-cations form dimers by C_py-H ⋯ F_Ar hydrogen-bonding interactions. Anions and cations stack in alternating layers which are nearly parallel to the bc plane of the crystallographic unit cell.

Original language	English
Pages (from-to)	m157-m159
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	59
Issue number	4
DOIs	https://doi.org/10.1107/S1600536803005270
State	Published - Apr 2003
Externally published	Yes

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title = "The 1:2 bis(maleonitriledithiolato)-palladium(II) complex of the N-(2-fluoro-4-bromobenzyl)pyridinium cation",

abstract = "In the title salt, (C12H10BrFN)2[Pd(C 4N2S2)2] or [N-(2-fluoro-4- bromobenzyl)pyridinium]2[Pd(mnt)2], where mnt2- denotes maleonitriledithiolate, the Pd2+ ion is coordinated by four S atoms of two mnt2- ligands in a planar geometry. The asymmetric unit is composed of one N-(2-fluoro-4-bromo-benzyl)pyridinium cation and one-half [Pd(mnt)2]2- anion. The adjacent counter-cations form dimers by Cpy-H ⋯ FAr hydrogen-bonding interactions. Anions and cations stack in alternating layers which are nearly parallel to the bc plane of the crystallographic unit cell.",

author = "Youcun Chen and Jingli Xie and Xiaoming Ren and Guangxiang Liu",

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T1 - The 1:2 bis(maleonitriledithiolato)-palladium(II) complex of the N-(2-fluoro-4-bromobenzyl)pyridinium cation

AU - Chen, Youcun

AU - Xie, Jingli

AU - Ren, Xiaoming

AU - Liu, Guangxiang

PY - 2003/4

Y1 - 2003/4

N2 - In the title salt, (C12H10BrFN)2[Pd(C 4N2S2)2] or [N-(2-fluoro-4- bromobenzyl)pyridinium]2[Pd(mnt)2], where mnt2- denotes maleonitriledithiolate, the Pd2+ ion is coordinated by four S atoms of two mnt2- ligands in a planar geometry. The asymmetric unit is composed of one N-(2-fluoro-4-bromo-benzyl)pyridinium cation and one-half [Pd(mnt)2]2- anion. The adjacent counter-cations form dimers by Cpy-H ⋯ FAr hydrogen-bonding interactions. Anions and cations stack in alternating layers which are nearly parallel to the bc plane of the crystallographic unit cell.

AB - In the title salt, (C12H10BrFN)2[Pd(C 4N2S2)2] or [N-(2-fluoro-4- bromobenzyl)pyridinium]2[Pd(mnt)2], where mnt2- denotes maleonitriledithiolate, the Pd2+ ion is coordinated by four S atoms of two mnt2- ligands in a planar geometry. The asymmetric unit is composed of one N-(2-fluoro-4-bromo-benzyl)pyridinium cation and one-half [Pd(mnt)2]2- anion. The adjacent counter-cations form dimers by Cpy-H ⋯ FAr hydrogen-bonding interactions. Anions and cations stack in alternating layers which are nearly parallel to the bc plane of the crystallographic unit cell.

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The 1:2 bis(maleonitriledithiolato)-palladium(II) complex of the N-(2-fluoro-4-bromobenzyl)pyridinium cation

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