The first one-dimensional molecular material featuring maleonitriledithiolate as a subunit exhibiting metamagnetic-like behavior

Jingli Xie; Xiaoming Ren; Song Gao; Wenwei Zhang; Yizhi Li; Changsheng Lu; Chunlin Ni; Wenlong Liu; Qingjin Meng; Yuangen Yao

doi:10.1002/ejic.200300108

The first one-dimensional molecular material featuring maleonitriledithiolate as a subunit exhibiting metamagnetic-like behavior

Jingli Xie, Xiaoming Ren, Song Gao, Wenwei Zhang, Yizhi Li, Changsheng Lu, Chunlin Ni, Wenlong Liu, Qingjin Meng, Yuangen Yao

Research output: Contribution to journal › Article › peer-review

66 Scopus citations

Abstract

An ion-pair complex [FBzPyNH₂][Ni(mnt)₂] {[FBzPyNH₂]⁺ = [1-(4′-fluorobenzyl)-4-amino]pyridinium and mnt^2- = maleonitriledithiolate} has been obtained by 12 oxidation of the corresponding dianion complex. It forms a well-segregated stacking column structure in the solid state, and exhibits antiferromagnetic ordering below 2.5 K. It is the first complex in this series of complexes containing a maleonitriledithiolate dianion that exhibits metamagnetism.

Original language	English
Pages (from-to)	2393-2396
Number of pages	4
Journal	European Journal of Inorganic Chemistry
Issue number	13
DOIs	https://doi.org/10.1002/ejic.200300108
State	Published - 7 Jul 2003
Externally published	Yes

Keywords

Crystal structure
Magnetic properties
Maleonitriledithiolate
Nickel

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10.1002/ejic.200300108

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title = "The first one-dimensional molecular material featuring maleonitriledithiolate as a subunit exhibiting metamagnetic-like behavior",

abstract = "An ion-pair complex [FBzPyNH2][Ni(mnt)2] {[FBzPyNH2]+ = [1-(4′-fluorobenzyl)-4-amino]pyridinium and mnt2- = maleonitriledithiolate} has been obtained by 12 oxidation of the corresponding dianion complex. It forms a well-segregated stacking column structure in the solid state, and exhibits antiferromagnetic ordering below 2.5 K. It is the first complex in this series of complexes containing a maleonitriledithiolate dianion that exhibits metamagnetism.",

keywords = "Crystal structure, Magnetic properties, Maleonitriledithiolate, Nickel",

author = "Jingli Xie and Xiaoming Ren and Song Gao and Wenwei Zhang and Yizhi Li and Changsheng Lu and Chunlin Ni and Wenlong Liu and Qingjin Meng and Yuangen Yao",

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doi = "10.1002/ejic.200300108",

language = "英语",

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TY - JOUR

T1 - The first one-dimensional molecular material featuring maleonitriledithiolate as a subunit exhibiting metamagnetic-like behavior

AU - Xie, Jingli

AU - Ren, Xiaoming

AU - Gao, Song

AU - Zhang, Wenwei

AU - Li, Yizhi

AU - Lu, Changsheng

AU - Ni, Chunlin

AU - Liu, Wenlong

AU - Meng, Qingjin

AU - Yao, Yuangen

PY - 2003/7/7

Y1 - 2003/7/7

N2 - An ion-pair complex [FBzPyNH2][Ni(mnt)2] {[FBzPyNH2]+ = [1-(4′-fluorobenzyl)-4-amino]pyridinium and mnt2- = maleonitriledithiolate} has been obtained by 12 oxidation of the corresponding dianion complex. It forms a well-segregated stacking column structure in the solid state, and exhibits antiferromagnetic ordering below 2.5 K. It is the first complex in this series of complexes containing a maleonitriledithiolate dianion that exhibits metamagnetism.

AB - An ion-pair complex [FBzPyNH2][Ni(mnt)2] {[FBzPyNH2]+ = [1-(4′-fluorobenzyl)-4-amino]pyridinium and mnt2- = maleonitriledithiolate} has been obtained by 12 oxidation of the corresponding dianion complex. It forms a well-segregated stacking column structure in the solid state, and exhibits antiferromagnetic ordering below 2.5 K. It is the first complex in this series of complexes containing a maleonitriledithiolate dianion that exhibits metamagnetism.

KW - Crystal structure

KW - Magnetic properties

KW - Maleonitriledithiolate

KW - Nickel

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U2 - 10.1002/ejic.200300108

DO - 10.1002/ejic.200300108

M3 - 文章

AN - SCOPUS:0042808532

SN - 1434-1948

SP - 2393

EP - 2396

JO - European Journal of Inorganic Chemistry

JF - European Journal of Inorganic Chemistry

IS - 13

ER -

The first one-dimensional molecular material featuring maleonitriledithiolate as a subunit exhibiting metamagnetic-like behavior

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Keywords

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