摘要
An ion-pair complex [FBzPyNH2][Ni(mnt)2] {[FBzPyNH2]+ = [1-(4′-fluorobenzyl)-4-amino]pyridinium and mnt2- = maleonitriledithiolate} has been obtained by 12 oxidation of the corresponding dianion complex. It forms a well-segregated stacking column structure in the solid state, and exhibits antiferromagnetic ordering below 2.5 K. It is the first complex in this series of complexes containing a maleonitriledithiolate dianion that exhibits metamagnetism.
源语言 | 英语 |
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页(从-至) | 2393-2396 |
页数 | 4 |
期刊 | European Journal of Inorganic Chemistry |
期 | 13 |
DOI | |
出版状态 | 已出版 - 7 7月 2003 |
已对外发布 | 是 |