The first one-dimensional molecular material featuring maleonitriledithiolate as a subunit exhibiting metamagnetic-like behavior

Jingli Xie, Xiaoming Ren, Song Gao, Wenwei Zhang, Yizhi Li, Changsheng Lu, Chunlin Ni, Wenlong Liu, Qingjin Meng, Yuangen Yao

科研成果: 期刊稿件文章同行评审

66 引用 (Scopus)

摘要

An ion-pair complex [FBzPyNH2][Ni(mnt)2] {[FBzPyNH2]+ = [1-(4′-fluorobenzyl)-4-amino]pyridinium and mnt2- = maleonitriledithiolate} has been obtained by 12 oxidation of the corresponding dianion complex. It forms a well-segregated stacking column structure in the solid state, and exhibits antiferromagnetic ordering below 2.5 K. It is the first complex in this series of complexes containing a maleonitriledithiolate dianion that exhibits metamagnetism.

源语言英语
页(从-至)2393-2396
页数4
期刊European Journal of Inorganic Chemistry
13
DOI
出版状态已出版 - 7 7月 2003
已对外发布

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