Triple bonding between beryllium and nitrogen in HNBeCO

Lina Wang; Sudip Pan; Guanjun Wang; Xiaoqing Zeng; Mingfei Zhou; Gernot Frenking

doi:10.1039/d2cc02969c

Triple bonding between beryllium and nitrogen in HNBeCO

Lina Wang, Sudip Pan, Guanjun Wang, Xiaoqing Zeng, Mingfei Zhou, Gernot Frenking

School of Chemistry and Moleculai Engineering

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

The HNBeCO complex is generated via the reaction of a beryllium atom with a HNCO molecule in a solid neon matrix, which is identified via infrared absorption spectroscopy with isotopic substitutions. The complex is characterized to have a linear structure with a very short Be-N bond distance. Bonding analyses indicate that the complex involves an unprecedented HNBeCO triple bond consisting of two degenerate electron-sharing π bonds and a dative σ bond with the π bonds being much stronger than the σ bond.

Original language	English
Pages (from-to)	8532-8535
Number of pages	4
Journal	Chemical Communications
Volume	58
Issue number	61
DOIs	https://doi.org/10.1039/d2cc02969c
State	Published - 27 Jun 2022

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title = "Triple bonding between beryllium and nitrogen in HNBeCO",

abstract = "The HNBeCO complex is generated via the reaction of a beryllium atom with a HNCO molecule in a solid neon matrix, which is identified via infrared absorption spectroscopy with isotopic substitutions. The complex is characterized to have a linear structure with a very short Be-N bond distance. Bonding analyses indicate that the complex involves an unprecedented HNBeCO triple bond consisting of two degenerate electron-sharing π bonds and a dative σ bond with the π bonds being much stronger than the σ bond.",

author = "Lina Wang and Sudip Pan and Guanjun Wang and Xiaoqing Zeng and Mingfei Zhou and Gernot Frenking",

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T1 - Triple bonding between beryllium and nitrogen in HNBeCO

AU - Wang, Lina

AU - Pan, Sudip

AU - Wang, Guanjun

AU - Zeng, Xiaoqing

AU - Zhou, Mingfei

AU - Frenking, Gernot

PY - 2022/6/27

Y1 - 2022/6/27

N2 - The HNBeCO complex is generated via the reaction of a beryllium atom with a HNCO molecule in a solid neon matrix, which is identified via infrared absorption spectroscopy with isotopic substitutions. The complex is characterized to have a linear structure with a very short Be-N bond distance. Bonding analyses indicate that the complex involves an unprecedented HNBeCO triple bond consisting of two degenerate electron-sharing π bonds and a dative σ bond with the π bonds being much stronger than the σ bond.

AB - The HNBeCO complex is generated via the reaction of a beryllium atom with a HNCO molecule in a solid neon matrix, which is identified via infrared absorption spectroscopy with isotopic substitutions. The complex is characterized to have a linear structure with a very short Be-N bond distance. Bonding analyses indicate that the complex involves an unprecedented HNBeCO triple bond consisting of two degenerate electron-sharing π bonds and a dative σ bond with the π bonds being much stronger than the σ bond.

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U2 - 10.1039/d2cc02969c

DO - 10.1039/d2cc02969c

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AN - SCOPUS:85133826142

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VL - 58

SP - 8532

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JO - Chemical Communications

JF - Chemical Communications

IS - 61

ER -

Triple bonding between beryllium and nitrogen in HNBeCO

Abstract

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