Triple bonding between beryllium and nitrogen in HNBeCO

Lina Wang; Sudip Pan; Guanjun Wang; Xiaoqing Zeng; Mingfei Zhou; Gernot Frenking

doi:10.1039/d2cc02969c

Triple bonding between beryllium and nitrogen in HNBeCO

Lina Wang, Sudip Pan, Guanjun Wang, Xiaoqing Zeng, Mingfei Zhou, Gernot Frenking

化学与分子工程学院

科研成果: 期刊稿件 › 文章 › 同行评审

8 引用（Scopus）

摘要

The HNBeCO complex is generated via the reaction of a beryllium atom with a HNCO molecule in a solid neon matrix, which is identified via infrared absorption spectroscopy with isotopic substitutions. The complex is characterized to have a linear structure with a very short Be-N bond distance. Bonding analyses indicate that the complex involves an unprecedented HNBeCO triple bond consisting of two degenerate electron-sharing π bonds and a dative σ bond with the π bonds being much stronger than the σ bond.

源语言	英语
页（从-至）	8532-8535
页数	4
期刊	Chemical Communications
卷	58
期	61
DOI	https://doi.org/10.1039/d2cc02969c
出版状态	已出版 - 27 6月 2022

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10.1039/d2cc02969c

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abstract = "The HNBeCO complex is generated via the reaction of a beryllium atom with a HNCO molecule in a solid neon matrix, which is identified via infrared absorption spectroscopy with isotopic substitutions. The complex is characterized to have a linear structure with a very short Be-N bond distance. Bonding analyses indicate that the complex involves an unprecedented HNBeCO triple bond consisting of two degenerate electron-sharing π bonds and a dative σ bond with the π bonds being much stronger than the σ bond.",

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AU - Wang, Lina

AU - Pan, Sudip

AU - Wang, Guanjun

AU - Zeng, Xiaoqing

AU - Zhou, Mingfei

AU - Frenking, Gernot

PY - 2022/6/27

Y1 - 2022/6/27

N2 - The HNBeCO complex is generated via the reaction of a beryllium atom with a HNCO molecule in a solid neon matrix, which is identified via infrared absorption spectroscopy with isotopic substitutions. The complex is characterized to have a linear structure with a very short Be-N bond distance. Bonding analyses indicate that the complex involves an unprecedented HNBeCO triple bond consisting of two degenerate electron-sharing π bonds and a dative σ bond with the π bonds being much stronger than the σ bond.

AB - The HNBeCO complex is generated via the reaction of a beryllium atom with a HNCO molecule in a solid neon matrix, which is identified via infrared absorption spectroscopy with isotopic substitutions. The complex is characterized to have a linear structure with a very short Be-N bond distance. Bonding analyses indicate that the complex involves an unprecedented HNBeCO triple bond consisting of two degenerate electron-sharing π bonds and a dative σ bond with the π bonds being much stronger than the σ bond.

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Triple bonding between beryllium and nitrogen in HNBeCO

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