摘要
The HNBeCO complex is generated via the reaction of a beryllium atom with a HNCO molecule in a solid neon matrix, which is identified via infrared absorption spectroscopy with isotopic substitutions. The complex is characterized to have a linear structure with a very short Be-N bond distance. Bonding analyses indicate that the complex involves an unprecedented HNBeCO triple bond consisting of two degenerate electron-sharing π bonds and a dative σ bond with the π bonds being much stronger than the σ bond.
源语言 | 英语 |
---|---|
页(从-至) | 8532-8535 |
页数 | 4 |
期刊 | Chemical Communications |
卷 | 58 |
期 | 61 |
DOI | |
出版状态 | 已出版 - 27 6月 2022 |