Triple bonding between beryllium and nitrogen in HNBeCO

Lina Wang, Sudip Pan, Guanjun Wang, Xiaoqing Zeng, Mingfei Zhou, Gernot Frenking

科研成果: 期刊稿件文章同行评审

8 引用 (Scopus)

摘要

The HNBeCO complex is generated via the reaction of a beryllium atom with a HNCO molecule in a solid neon matrix, which is identified via infrared absorption spectroscopy with isotopic substitutions. The complex is characterized to have a linear structure with a very short Be-N bond distance. Bonding analyses indicate that the complex involves an unprecedented HNBeCO triple bond consisting of two degenerate electron-sharing π bonds and a dative σ bond with the π bonds being much stronger than the σ bond.

源语言英语
页(从-至)8532-8535
页数4
期刊Chemical Communications
58
61
DOI
出版状态已出版 - 27 6月 2022

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