Two novel three-dimensional coordination polymers based on metal clusters: Hydrothermal syntheses, crystal structures and luminescence

Guang Xiang Liu; Kun Zhu; Hong Chen; Rong Yi Huang; Heng Xu; Xiao Ming Ren

doi:10.1016/j.ica.2008.08.010

Two novel three-dimensional coordination polymers based on metal clusters: Hydrothermal syntheses, crystal structures and luminescence

Guang Xiang Liu, Kun Zhu, Hong Chen, Rong Yi Huang, Heng Xu, Xiao Ming Ren

School of Chemistry and Moleculai Engineering

Anqing Normal University

Research output: Contribution to journal › Article › peer-review

39 Scopus citations

Abstract

Two novel coordination polymers with interesting supramolecular architecture, [Zn₂(OH)(BTC)(bix)] (1) and [Cd₂(CDC)₂(bix)₂] (2) (H₃BTC = 1,3,5-benzenetricarboxylic acid, H₂CDC = trans-1,4-cyclohexanedicarboxylic acid and bix = 1,2-bis(imidazol-1-ylmethyl)benzene) have been obtained via hydrothermal reaction and characterized by elemental analysis, IR and single-crystal X-ray diffraction. Complex 1 features a 3D network with one of the scarce (3,8)-connected (4³)₂(4⁶.6¹⁸.8⁴) topology based on the rare CdI₂-type layer constructed from secondary building units (SBUs) of zinc clusters. While 2 exhibits a scarcely reported eight-connected 3⁶.4¹⁶.5⁶ net with dinuclear cadmium clusters as secondary building units. The luminescent properties of 1 and 2 along with the bix ligand in the solid state were investigated.

Original language	English
Pages (from-to)	1605-1610
Number of pages	6
Journal	Inorganica Chimica Acta
Volume	362
Issue number	5
DOIs	https://doi.org/10.1016/j.ica.2008.08.010
State	Published - 1 Apr 2009

Keywords

Bis(imidazole) ligand
Coordination polymer
Luminescence
Topology

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title = "Two novel three-dimensional coordination polymers based on metal clusters: Hydrothermal syntheses, crystal structures and luminescence",

abstract = "Two novel coordination polymers with interesting supramolecular architecture, [Zn2(OH)(BTC)(bix)] (1) and [Cd2(CDC)2(bix)2] (2) (H3BTC = 1,3,5-benzenetricarboxylic acid, H2CDC = trans-1,4-cyclohexanedicarboxylic acid and bix = 1,2-bis(imidazol-1-ylmethyl)benzene) have been obtained via hydrothermal reaction and characterized by elemental analysis, IR and single-crystal X-ray diffraction. Complex 1 features a 3D network with one of the scarce (3,8)-connected (43)2(46.618.84) topology based on the rare CdI2-type layer constructed from secondary building units (SBUs) of zinc clusters. While 2 exhibits a scarcely reported eight-connected 36.416.56 net with dinuclear cadmium clusters as secondary building units. The luminescent properties of 1 and 2 along with the bix ligand in the solid state were investigated.",

keywords = "Bis(imidazole) ligand, Coordination polymer, Luminescence, Topology",

author = "Liu, {Guang Xiang} and Kun Zhu and Hong Chen and Huang, {Rong Yi} and Heng Xu and Ren, {Xiao Ming}",

year = "2009",

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day = "1",

doi = "10.1016/j.ica.2008.08.010",

language = "英语",

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pages = "1605--1610",

journal = "Inorganica Chimica Acta",

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TY - JOUR

T1 - Two novel three-dimensional coordination polymers based on metal clusters

T2 - Hydrothermal syntheses, crystal structures and luminescence

AU - Liu, Guang Xiang

AU - Zhu, Kun

AU - Chen, Hong

AU - Huang, Rong Yi

AU - Xu, Heng

AU - Ren, Xiao Ming

PY - 2009/4/1

Y1 - 2009/4/1

N2 - Two novel coordination polymers with interesting supramolecular architecture, [Zn2(OH)(BTC)(bix)] (1) and [Cd2(CDC)2(bix)2] (2) (H3BTC = 1,3,5-benzenetricarboxylic acid, H2CDC = trans-1,4-cyclohexanedicarboxylic acid and bix = 1,2-bis(imidazol-1-ylmethyl)benzene) have been obtained via hydrothermal reaction and characterized by elemental analysis, IR and single-crystal X-ray diffraction. Complex 1 features a 3D network with one of the scarce (3,8)-connected (43)2(46.618.84) topology based on the rare CdI2-type layer constructed from secondary building units (SBUs) of zinc clusters. While 2 exhibits a scarcely reported eight-connected 36.416.56 net with dinuclear cadmium clusters as secondary building units. The luminescent properties of 1 and 2 along with the bix ligand in the solid state were investigated.

AB - Two novel coordination polymers with interesting supramolecular architecture, [Zn2(OH)(BTC)(bix)] (1) and [Cd2(CDC)2(bix)2] (2) (H3BTC = 1,3,5-benzenetricarboxylic acid, H2CDC = trans-1,4-cyclohexanedicarboxylic acid and bix = 1,2-bis(imidazol-1-ylmethyl)benzene) have been obtained via hydrothermal reaction and characterized by elemental analysis, IR and single-crystal X-ray diffraction. Complex 1 features a 3D network with one of the scarce (3,8)-connected (43)2(46.618.84) topology based on the rare CdI2-type layer constructed from secondary building units (SBUs) of zinc clusters. While 2 exhibits a scarcely reported eight-connected 36.416.56 net with dinuclear cadmium clusters as secondary building units. The luminescent properties of 1 and 2 along with the bix ligand in the solid state were investigated.

KW - Bis(imidazole) ligand

KW - Coordination polymer

KW - Luminescence

KW - Topology

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U2 - 10.1016/j.ica.2008.08.010

DO - 10.1016/j.ica.2008.08.010

M3 - 文章

AN - SCOPUS:60849134577

SN - 0020-1693

VL - 362

SP - 1605

EP - 1610

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

IS - 5

ER -

Two novel three-dimensional coordination polymers based on metal clusters: Hydrothermal syntheses, crystal structures and luminescence

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Keywords

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