TY - JOUR
T1 - Two novel three-dimensional coordination polymers based on metal clusters
T2 - Hydrothermal syntheses, crystal structures and luminescence
AU - Liu, Guang Xiang
AU - Zhu, Kun
AU - Chen, Hong
AU - Huang, Rong Yi
AU - Xu, Heng
AU - Ren, Xiao Ming
PY - 2009/4/1
Y1 - 2009/4/1
N2 - Two novel coordination polymers with interesting supramolecular architecture, [Zn2(OH)(BTC)(bix)] (1) and [Cd2(CDC)2(bix)2] (2) (H3BTC = 1,3,5-benzenetricarboxylic acid, H2CDC = trans-1,4-cyclohexanedicarboxylic acid and bix = 1,2-bis(imidazol-1-ylmethyl)benzene) have been obtained via hydrothermal reaction and characterized by elemental analysis, IR and single-crystal X-ray diffraction. Complex 1 features a 3D network with one of the scarce (3,8)-connected (43)2(46.618.84) topology based on the rare CdI2-type layer constructed from secondary building units (SBUs) of zinc clusters. While 2 exhibits a scarcely reported eight-connected 36.416.56 net with dinuclear cadmium clusters as secondary building units. The luminescent properties of 1 and 2 along with the bix ligand in the solid state were investigated.
AB - Two novel coordination polymers with interesting supramolecular architecture, [Zn2(OH)(BTC)(bix)] (1) and [Cd2(CDC)2(bix)2] (2) (H3BTC = 1,3,5-benzenetricarboxylic acid, H2CDC = trans-1,4-cyclohexanedicarboxylic acid and bix = 1,2-bis(imidazol-1-ylmethyl)benzene) have been obtained via hydrothermal reaction and characterized by elemental analysis, IR and single-crystal X-ray diffraction. Complex 1 features a 3D network with one of the scarce (3,8)-connected (43)2(46.618.84) topology based on the rare CdI2-type layer constructed from secondary building units (SBUs) of zinc clusters. While 2 exhibits a scarcely reported eight-connected 36.416.56 net with dinuclear cadmium clusters as secondary building units. The luminescent properties of 1 and 2 along with the bix ligand in the solid state were investigated.
KW - Bis(imidazole) ligand
KW - Coordination polymer
KW - Luminescence
KW - Topology
UR - http://www.scopus.com/inward/record.url?scp=60849134577&partnerID=8YFLogxK
U2 - 10.1016/j.ica.2008.08.010
DO - 10.1016/j.ica.2008.08.010
M3 - 文章
AN - SCOPUS:60849134577
SN - 0020-1693
VL - 362
SP - 1605
EP - 1610
JO - Inorganica Chimica Acta
JF - Inorganica Chimica Acta
IS - 5
ER -