Visible light mediated regioselective 1,3-oxylallylation of aryl cyclopropanes under redox-neutral conditions

Ding Xing Wang; Hui Wang; Yao Xu; Chi Zhang; Chao Feng

doi:10.1039/d3qo00281k

Visible light mediated regioselective 1,3-oxylallylation of aryl cyclopropanes under redox-neutral conditions

Ding Xing Wang, Hui Wang, Yao Xu, Chi Zhang, Chao Feng

School of Chemistry and Moleculai Engineering

Nanjing Tech University

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

A photoredox catalysed 1,3-oxylallylation of aryl cyclopropanes was accomplished by reaction with carboxylic acids and allyl sulfones. The redox-neutral reaction proceeded in a highly regioselective manner under mild conditions with good functional group compatibility. Simple operation and successful application to the late-stage functionalization of several natural product and pharmaceutical molecule related carboxylic acids add extra merits to the current protocol.

Original language	English
Pages (from-to)	2147-2154
Number of pages	8
Journal	Organic Chemistry Frontiers
Volume	10
Issue number	9
DOIs	https://doi.org/10.1039/d3qo00281k
State	Published - 1 Apr 2023

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title = "Visible light mediated regioselective 1,3-oxylallylation of aryl cyclopropanes under redox-neutral conditions",

abstract = "A photoredox catalysed 1,3-oxylallylation of aryl cyclopropanes was accomplished by reaction with carboxylic acids and allyl sulfones. The redox-neutral reaction proceeded in a highly regioselective manner under mild conditions with good functional group compatibility. Simple operation and successful application to the late-stage functionalization of several natural product and pharmaceutical molecule related carboxylic acids add extra merits to the current protocol.",

author = "Wang, {Ding Xing} and Hui Wang and Yao Xu and Chi Zhang and Chao Feng",

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T1 - Visible light mediated regioselective 1,3-oxylallylation of aryl cyclopropanes under redox-neutral conditions

AU - Wang, Ding Xing

AU - Wang, Hui

AU - Xu, Yao

AU - Zhang, Chi

AU - Feng, Chao

PY - 2023/4/1

Y1 - 2023/4/1

N2 - A photoredox catalysed 1,3-oxylallylation of aryl cyclopropanes was accomplished by reaction with carboxylic acids and allyl sulfones. The redox-neutral reaction proceeded in a highly regioselective manner under mild conditions with good functional group compatibility. Simple operation and successful application to the late-stage functionalization of several natural product and pharmaceutical molecule related carboxylic acids add extra merits to the current protocol.

AB - A photoredox catalysed 1,3-oxylallylation of aryl cyclopropanes was accomplished by reaction with carboxylic acids and allyl sulfones. The redox-neutral reaction proceeded in a highly regioselective manner under mild conditions with good functional group compatibility. Simple operation and successful application to the late-stage functionalization of several natural product and pharmaceutical molecule related carboxylic acids add extra merits to the current protocol.

UR - http://www.scopus.com/inward/record.url?scp=85151816415&partnerID=8YFLogxK

U2 - 10.1039/d3qo00281k

DO - 10.1039/d3qo00281k

M3 - 文章

AN - SCOPUS:85151816415

SN - 2052-4110

VL - 10

SP - 2147

EP - 2154

JO - Organic Chemistry Frontiers

JF - Organic Chemistry Frontiers

IS - 9

ER -

Visible light mediated regioselective 1,3-oxylallylation of aryl cyclopropanes under redox-neutral conditions

Abstract

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