Difunctionalization of alkenes proceeding with radical 1,2-alkynyl migration in batch and continuous-flow modes

Ziren Mao, Yiliang Zhou, Jingming Zhang, Chengkou Liu, Chang Sheng Wang, Xiaobing Yang, Hong Qin, Zheng Fang, Kai Guo

科研成果: 期刊稿件文章同行评审

1 引用 (Scopus)

摘要

An efficient strategy to construct α-alkynyl ketones through electrochemical difunctionalization of alkenes was developed. This method is oxidant-free, metal-free, high-efficiency and eco-friendly, and offers rapid constructions of 1,2-alkynyl migration products through the radical process of 3-exo-dig cyclization. Moreover, the reaction could undergo a successful transformation under continuous-flow conditions.

源语言英语
页(从-至)1735-1740
页数6
期刊New Journal of Chemistry
48
4
DOI
出版状态已出版 - 2 12月 2023

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