Electrochemical Synthesis of Alkenylsulfonates from Alkynes, NaHSO3 and Alcohols

Xiaoman Wang, Qianqian Chen, Jinhang Zhou, Yi Hu, Shengqing Ye, Jie Wu

科研成果: 期刊稿件文章同行评审

4 引用 (Scopus)

摘要

Alkenylsulfonates are commonly encountered in medicinal chemistry, polymer chemistry, and organic synthesis. In this research, an electrochemical reaction involving alkynes, NaHSO3, and alcohols has been developed. This method yields functionalized alkenylsulfonates in good yields with broad functional group tolerance. Mechanism studies indicate that anodic oxidation of inorganic sulfite, radical insertion process, and HAT process are involved in this transformation.

源语言英语
页(从-至)292-296
页数5
期刊Chinese Journal of Chemistry
43
3
DOI
出版状态已出版 - 1 2月 2025

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