Influence of alumina binder content on catalytic properties of PtSnNa/AlSBA-15 catalysts

Yongzheng Duan; Yuming Zhou; Xiaoli Sheng; Yiwei Zhang; Shijian Zhou; Zewu Zhang

doi:10.1016/j.micromeso.2012.05.016

Influence of alumina binder content on catalytic properties of PtSnNa/AlSBA-15 catalysts

Yongzheng Duan, Yuming Zhou, Xiaoli Sheng, Yiwei Zhang, Shijian Zhou, Zewu Zhang

Southeast University, Nanjing

科研成果: 期刊稿件 › 文章 › 同行评审

21 引用（Scopus）

摘要

The influence of the amount of alumina binder on the catalytic properties of PtSnNa/AlSBA-15 catalysts for propane dehydrogenation was investigated. BET surface area measurement, catalyst particle mechanical strength, solid-state ²⁷Al MAS NMR spectroscopy, hydrogen chemisorption, NH ₃-TPD and XPS were used to characterize the catalysts. It can be observed that the mechanical strength of the agglomerated catalyst was higher than that of the nonagglomerated one. Among these catalysts studied, the PtSnNa/AlSBA-15 catalyst bound with 20 wt.% alumina binder showed the best catalytic performance in terms of propane conversion and selectivity to propene. The high catalytic performance may be due to relatively good Pt metal dispersion and/or the strong interaction between Pt and Sn, which were attributed to an increase in Al(IV) and Al(VI) species for the agglomerated catalyst.

源语言	英语
页（从-至）	33-39
页数	7
期刊	Microporous and Mesoporous Materials
卷	161
DOI	https://doi.org/10.1016/j.micromeso.2012.05.016
出版状态	已出版 - 1 10月 2012
已对外发布	是

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@article{0499de1856884aaba7c90275e7a6f7ff,

title = "Influence of alumina binder content on catalytic properties of PtSnNa/AlSBA-15 catalysts",

abstract = "The influence of the amount of alumina binder on the catalytic properties of PtSnNa/AlSBA-15 catalysts for propane dehydrogenation was investigated. BET surface area measurement, catalyst particle mechanical strength, solid-state 27Al MAS NMR spectroscopy, hydrogen chemisorption, NH 3-TPD and XPS were used to characterize the catalysts. It can be observed that the mechanical strength of the agglomerated catalyst was higher than that of the nonagglomerated one. Among these catalysts studied, the PtSnNa/AlSBA-15 catalyst bound with 20 wt.% alumina binder showed the best catalytic performance in terms of propane conversion and selectivity to propene. The high catalytic performance may be due to relatively good Pt metal dispersion and/or the strong interaction between Pt and Sn, which were attributed to an increase in Al(IV) and Al(VI) species for the agglomerated catalyst.",

keywords = "AlSBA-15, Binder, Propane dehydrogenation, Pt",

author = "Yongzheng Duan and Yuming Zhou and Xiaoli Sheng and Yiwei Zhang and Shijian Zhou and Zewu Zhang",

year = "2012",

month = oct,

day = "1",

doi = "10.1016/j.micromeso.2012.05.016",

language = "英语",

volume = "161",

pages = "33--39",

journal = "Microporous and Mesoporous Materials",

issn = "1387-1811",

publisher = "Elsevier B.V.",

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TY - JOUR

T1 - Influence of alumina binder content on catalytic properties of PtSnNa/AlSBA-15 catalysts

AU - Duan, Yongzheng

AU - Zhou, Yuming

AU - Sheng, Xiaoli

AU - Zhang, Yiwei

AU - Zhou, Shijian

AU - Zhang, Zewu

PY - 2012/10/1

Y1 - 2012/10/1

N2 - The influence of the amount of alumina binder on the catalytic properties of PtSnNa/AlSBA-15 catalysts for propane dehydrogenation was investigated. BET surface area measurement, catalyst particle mechanical strength, solid-state 27Al MAS NMR spectroscopy, hydrogen chemisorption, NH 3-TPD and XPS were used to characterize the catalysts. It can be observed that the mechanical strength of the agglomerated catalyst was higher than that of the nonagglomerated one. Among these catalysts studied, the PtSnNa/AlSBA-15 catalyst bound with 20 wt.% alumina binder showed the best catalytic performance in terms of propane conversion and selectivity to propene. The high catalytic performance may be due to relatively good Pt metal dispersion and/or the strong interaction between Pt and Sn, which were attributed to an increase in Al(IV) and Al(VI) species for the agglomerated catalyst.

AB - The influence of the amount of alumina binder on the catalytic properties of PtSnNa/AlSBA-15 catalysts for propane dehydrogenation was investigated. BET surface area measurement, catalyst particle mechanical strength, solid-state 27Al MAS NMR spectroscopy, hydrogen chemisorption, NH 3-TPD and XPS were used to characterize the catalysts. It can be observed that the mechanical strength of the agglomerated catalyst was higher than that of the nonagglomerated one. Among these catalysts studied, the PtSnNa/AlSBA-15 catalyst bound with 20 wt.% alumina binder showed the best catalytic performance in terms of propane conversion and selectivity to propene. The high catalytic performance may be due to relatively good Pt metal dispersion and/or the strong interaction between Pt and Sn, which were attributed to an increase in Al(IV) and Al(VI) species for the agglomerated catalyst.

KW - AlSBA-15

KW - Binder

KW - Propane dehydrogenation

KW - Pt

UR - http://www.scopus.com/inward/record.url?scp=84861978202&partnerID=8YFLogxK

U2 - 10.1016/j.micromeso.2012.05.016

DO - 10.1016/j.micromeso.2012.05.016

M3 - 文章

AN - SCOPUS:84861978202

SN - 1387-1811

VL - 161

SP - 33

EP - 39

JO - Microporous and Mesoporous Materials

JF - Microporous and Mesoporous Materials

ER -

Influence of alumina binder content on catalytic properties of PtSnNa/AlSBA-15 catalysts

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