Iron- or silver-catalyzed oxidative fluorination of cyclopropanols for the synthesis of β-fluoroketones

Shichao Ren; Chao Feng; Teck Peng Loh

doi:10.1039/c5ob00632e

Iron- or silver-catalyzed oxidative fluorination of cyclopropanols for the synthesis of β-fluoroketones

Shichao Ren, Chao Feng, Teck Peng Loh

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122 引用（Scopus）

摘要

The Fe^III- or Ag^I-catalyzed oxidative fluorination of cyclopropanols via radical rearrangement is disclosed. This process features a straightforward and highly effective protocol for the site-specific synthesis of β-fluoroketones and represents an expedient method for the synthesis of γ-, δ- and ε-fluoroketones. Notably, this reaction proceeds at room temperature and tolerates a diverse array of cyclopropanols.

源语言	英语
页（从-至）	5105-5109
页数	5
期刊	Organic and Biomolecular Chemistry
卷	13
期	18
DOI	https://doi.org/10.1039/c5ob00632e
出版状态	已出版 - 14 5月 2015
已对外发布	是

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abstract = "The FeIII- or AgI-catalyzed oxidative fluorination of cyclopropanols via radical rearrangement is disclosed. This process features a straightforward and highly effective protocol for the site-specific synthesis of β-fluoroketones and represents an expedient method for the synthesis of γ-, δ- and ε-fluoroketones. Notably, this reaction proceeds at room temperature and tolerates a diverse array of cyclopropanols.",

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T1 - Iron- or silver-catalyzed oxidative fluorination of cyclopropanols for the synthesis of β-fluoroketones

AU - Ren, Shichao

AU - Feng, Chao

AU - Loh, Teck Peng

N1 - Publisher Copyright: © The Royal Society of Chemistry 2015.

PY - 2015/5/14

Y1 - 2015/5/14

N2 - The FeIII- or AgI-catalyzed oxidative fluorination of cyclopropanols via radical rearrangement is disclosed. This process features a straightforward and highly effective protocol for the site-specific synthesis of β-fluoroketones and represents an expedient method for the synthesis of γ-, δ- and ε-fluoroketones. Notably, this reaction proceeds at room temperature and tolerates a diverse array of cyclopropanols.

AB - The FeIII- or AgI-catalyzed oxidative fluorination of cyclopropanols via radical rearrangement is disclosed. This process features a straightforward and highly effective protocol for the site-specific synthesis of β-fluoroketones and represents an expedient method for the synthesis of γ-, δ- and ε-fluoroketones. Notably, this reaction proceeds at room temperature and tolerates a diverse array of cyclopropanols.

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U2 - 10.1039/c5ob00632e

DO - 10.1039/c5ob00632e

M3 - 文章

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AN - SCOPUS:84928920245

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JO - Organic and Biomolecular Chemistry

JF - Organic and Biomolecular Chemistry

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ER -

Iron- or silver-catalyzed oxidative fluorination of cyclopropanols for the synthesis of β-fluoroketones

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