Regio-and stereoselective C(sp2)-H acylation of enamides with aldehydes: Via transition-metal-free photoredox catalysis

Kai Zhao, Xiao Chen Zhang, Ji Yu Tao, Xian Dan Wu, Jia Xu Wu, Wei Ming Li, Tong Hao Zhu, Teck Peng Loh

科研成果: 期刊稿件文章同行评审

43 引用 (Scopus)

摘要

A straightforward and efficient C(sp2)-H acylation of enamides with aldehydes via transition-metal-free photoredox catalysis is demonstrated. The transformation proceeded smoothly without resorting to expensive and potentially toxic iridium or ruthenium polypyridyl-based photocatalysts under mild conditions, furnishing a diverse range of synthetically crucial, geometrically defined β-acylated enamides in a stereoselective and regioselective manner.

源语言英语
页(从-至)5497-5503
页数7
期刊Green Chemistry
22
16
DOI
出版状态已出版 - 21 8月 2020

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