Transalkylation via C-N Bond Cleavage of Amines Catalyzed by Super Organophotoreductant CBZ6

Yong Ze Chen, Yi Ming Chen, Yuan Hu, Jian Ping Qu, Yan Biao Kang

科研成果: 期刊稿件文章同行评审

8 引用 (Scopus)

摘要

The super organoreductant CBZ6-catalyzed tandem transalkylation-cyclization using amines as traceless radical donors and stabilizer is reported. The later-stage breaking of an N-C bond enables the transalkylation with a secondary amine as the leaving moiety. A wide range of tertiary amines were used as alkyl radical donors for the C1-C8 alkyls. This traceless stabilizer also enabled the transalkylation with methyl radical, which is normally not possible because of the instability of methyl radical.

源语言英语
页(从-至)7518-7522
页数5
期刊Organic Letters
25
41
DOI
出版状态已出版 - 20 10月 2023

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