Abstract
A copper-catalyzed silylation of propargyl dichlorides was developed to access chloro-substituted allenylsilanes under mild reaction conditions. Moreover, enantioenriched chloro-substituted allenylsilanes can be synthesized in moderate to high yields and good enantioselectivities with this protocol.
Original language | English |
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Pages (from-to) | 16538-16542 |
Number of pages | 5 |
Journal | Angewandte Chemie - International Edition |
Volume | 58 |
Issue number | 46 |
DOIs | |
State | Published - 11 Nov 2019 |
Externally published | Yes |
Keywords
- allenes
- copper
- enantioselectivity
- silanes
- synthetic methods