Copper-Catalyzed Asymmetric Silylation of Propargyl Dichlorides: Access to Enantioenriched Functionalized Allenylsilanes

Zheng Li Liu, Chao Yang, Qi Yan Xue, Meng Zhao, Cui Cui Shan, Yun He Xu, Teck Peng Loh

科研成果: 期刊稿件文章同行评审

46 引用 (Scopus)

摘要

A copper-catalyzed silylation of propargyl dichlorides was developed to access chloro-substituted allenylsilanes under mild reaction conditions. Moreover, enantioenriched chloro-substituted allenylsilanes can be synthesized in moderate to high yields and good enantioselectivities with this protocol.

源语言英语
页(从-至)16538-16542
页数5
期刊Angewandte Chemie - International Edition
58
46
DOI
出版状态已出版 - 11 11月 2019
已对外发布

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