Highly efficient chemical kinetic resolution of bishomoallylic alcohols: Synthesis of (R)-sulcatol

Shui Ling Chen; Qi Ying Hu; Teck Peng Loh

doi:10.1021/ol048608q

Highly efficient chemical kinetic resolution of bishomoallylic alcohols: Synthesis of (R)-sulcatol

Shui Ling Chen, Qi Ying Hu, Teck Peng Loh

Research output: Contribution to journal › Article › peer-review

19 Scopus citations

Abstract

(Chemical Equation Presented) A highly efficient chemical kinetic resolution of bishomoallylic alcohols was developed when the alcohols underwent In(OTf)₃-catalyzed 3,5-oxonium-ene-type cyclization with steroidal aldehyde 2. Consistently high enantiomeric excess (up to >99%) was obtained.

Original language	English
Pages (from-to)	3365-3367
Number of pages	3
Journal	Organic Letters
Volume	6
Issue number	19
DOIs	https://doi.org/10.1021/ol048608q
State	Published - 16 Sep 2004
Externally published	Yes

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@article{016522fb1ba345bbbe641ae6ae4d0836,

title = "Highly efficient chemical kinetic resolution of bishomoallylic alcohols: Synthesis of (R)-sulcatol",

abstract = "(Chemical Equation Presented) A highly efficient chemical kinetic resolution of bishomoallylic alcohols was developed when the alcohols underwent In(OTf)3-catalyzed 3,5-oxonium-ene-type cyclization with steroidal aldehyde 2. Consistently high enantiomeric excess (up to >99%) was obtained.",

author = "Chen, {Shui Ling} and Hu, {Qi Ying} and Loh, {Teck Peng}",

year = "2004",

month = sep,

day = "16",

doi = "10.1021/ol048608q",

language = "英语",

volume = "6",

pages = "3365--3367",

journal = "Organic Letters",

issn = "1523-7060",

publisher = "American Chemical Society",

number = "19",

}

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T1 - Highly efficient chemical kinetic resolution of bishomoallylic alcohols

T2 - Synthesis of (R)-sulcatol

AU - Chen, Shui Ling

AU - Hu, Qi Ying

AU - Loh, Teck Peng

PY - 2004/9/16

Y1 - 2004/9/16

N2 - (Chemical Equation Presented) A highly efficient chemical kinetic resolution of bishomoallylic alcohols was developed when the alcohols underwent In(OTf)3-catalyzed 3,5-oxonium-ene-type cyclization with steroidal aldehyde 2. Consistently high enantiomeric excess (up to >99%) was obtained.

AB - (Chemical Equation Presented) A highly efficient chemical kinetic resolution of bishomoallylic alcohols was developed when the alcohols underwent In(OTf)3-catalyzed 3,5-oxonium-ene-type cyclization with steroidal aldehyde 2. Consistently high enantiomeric excess (up to >99%) was obtained.

UR - http://www.scopus.com/inward/record.url?scp=4644221820&partnerID=8YFLogxK

U2 - 10.1021/ol048608q

DO - 10.1021/ol048608q

M3 - 文章

C2 - 15355053

AN - SCOPUS:4644221820

SN - 1523-7060

VL - 6

SP - 3365

EP - 3367

JO - Organic Letters

JF - Organic Letters

IS - 19

ER -

Highly efficient chemical kinetic resolution of bishomoallylic alcohols: Synthesis of (R)-sulcatol

Abstract

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