Highly efficient chemical kinetic resolution of bishomoallylic alcohols: Synthesis of (R)-sulcatol

Shui Ling Chen; Qi Ying Hu; Teck Peng Loh

doi:10.1021/ol048608q

Highly efficient chemical kinetic resolution of bishomoallylic alcohols: Synthesis of (R)-sulcatol

Shui Ling Chen, Qi Ying Hu, Teck Peng Loh

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19 引用（Scopus）

摘要

(Chemical Equation Presented) A highly efficient chemical kinetic resolution of bishomoallylic alcohols was developed when the alcohols underwent In(OTf)₃-catalyzed 3,5-oxonium-ene-type cyclization with steroidal aldehyde 2. Consistently high enantiomeric excess (up to >99%) was obtained.

源语言	英语
页（从-至）	3365-3367
页数	3
期刊	Organic Letters
卷	6
期	19
DOI	https://doi.org/10.1021/ol048608q
出版状态	已出版 - 16 9月 2004
已对外发布	是

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10.1021/ol048608q

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title = "Highly efficient chemical kinetic resolution of bishomoallylic alcohols: Synthesis of (R)-sulcatol",

abstract = "(Chemical Equation Presented) A highly efficient chemical kinetic resolution of bishomoallylic alcohols was developed when the alcohols underwent In(OTf)3-catalyzed 3,5-oxonium-ene-type cyclization with steroidal aldehyde 2. Consistently high enantiomeric excess (up to >99%) was obtained.",

author = "Chen, {Shui Ling} and Hu, {Qi Ying} and Loh, {Teck Peng}",

year = "2004",

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T1 - Highly efficient chemical kinetic resolution of bishomoallylic alcohols

T2 - Synthesis of (R)-sulcatol

AU - Chen, Shui Ling

AU - Hu, Qi Ying

AU - Loh, Teck Peng

PY - 2004/9/16

Y1 - 2004/9/16

N2 - (Chemical Equation Presented) A highly efficient chemical kinetic resolution of bishomoallylic alcohols was developed when the alcohols underwent In(OTf)3-catalyzed 3,5-oxonium-ene-type cyclization with steroidal aldehyde 2. Consistently high enantiomeric excess (up to >99%) was obtained.

AB - (Chemical Equation Presented) A highly efficient chemical kinetic resolution of bishomoallylic alcohols was developed when the alcohols underwent In(OTf)3-catalyzed 3,5-oxonium-ene-type cyclization with steroidal aldehyde 2. Consistently high enantiomeric excess (up to >99%) was obtained.

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U2 - 10.1021/ol048608q

DO - 10.1021/ol048608q

M3 - 文章

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AN - SCOPUS:4644221820

SN - 1523-7060

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SP - 3365

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JO - Organic Letters

JF - Organic Letters

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ER -

Highly efficient chemical kinetic resolution of bishomoallylic alcohols: Synthesis of (R)-sulcatol

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