Palladium-catalyzed alkenyl C-H bond sulfonylation reaction using organosulfonyl chlorides

Yun He Xu; Min Wang; Ping Lu; Teck Peng Loh

doi:10.1016/j.tet.2013.01.071

Palladium-catalyzed alkenyl C-H bond sulfonylation reaction using organosulfonyl chlorides

Yun He Xu, Min Wang, Ping Lu, Teck Peng Loh

Research output: Contribution to journal › Article › peer-review

40 Scopus citations

Abstract

A Pd-catalyzed alkenyl C-H bond direct sulfonylation of vinyl pyridine and enamides was developed. Various arylsulfonyl chlorides were tested in this reaction and the desired products were obtained in good yields. Moreover, the alkyl sulfonyl chloride could also be used though the yield was lower. A possible Pd(II)/Pd(IV) catalytic pathway involved in this coupling reaction was proposed.

Original language	English
Pages (from-to)	4403-4407
Number of pages	5
Journal	Tetrahedron
Volume	69
Issue number	22
DOIs	https://doi.org/10.1016/j.tet.2013.01.071
State	Published - 3 Jun 2013
Externally published	Yes

Keywords

Coupling
Enamide
Palladium
Sulfonylation
Vinyl pyridine

Access to Document

10.1016/j.tet.2013.01.071

Cite this

@article{e8e2b153096f46b98fa7a409905b6180,

title = "Palladium-catalyzed alkenyl C-H bond sulfonylation reaction using organosulfonyl chlorides",

abstract = "A Pd-catalyzed alkenyl C-H bond direct sulfonylation of vinyl pyridine and enamides was developed. Various arylsulfonyl chlorides were tested in this reaction and the desired products were obtained in good yields. Moreover, the alkyl sulfonyl chloride could also be used though the yield was lower. A possible Pd(II)/Pd(IV) catalytic pathway involved in this coupling reaction was proposed.",

keywords = "Coupling, Enamide, Palladium, Sulfonylation, Vinyl pyridine",

author = "Xu, {Yun He} and Min Wang and Ping Lu and Loh, {Teck Peng}",

year = "2013",

month = jun,

day = "3",

doi = "10.1016/j.tet.2013.01.071",

language = "英语",

volume = "69",

pages = "4403--4407",

journal = "Tetrahedron",

issn = "0040-4020",

publisher = "Elsevier Ltd",

number = "22",

}

TY - JOUR

T1 - Palladium-catalyzed alkenyl C-H bond sulfonylation reaction using organosulfonyl chlorides

AU - Xu, Yun He

AU - Wang, Min

AU - Lu, Ping

AU - Loh, Teck Peng

PY - 2013/6/3

Y1 - 2013/6/3

N2 - A Pd-catalyzed alkenyl C-H bond direct sulfonylation of vinyl pyridine and enamides was developed. Various arylsulfonyl chlorides were tested in this reaction and the desired products were obtained in good yields. Moreover, the alkyl sulfonyl chloride could also be used though the yield was lower. A possible Pd(II)/Pd(IV) catalytic pathway involved in this coupling reaction was proposed.

AB - A Pd-catalyzed alkenyl C-H bond direct sulfonylation of vinyl pyridine and enamides was developed. Various arylsulfonyl chlorides were tested in this reaction and the desired products were obtained in good yields. Moreover, the alkyl sulfonyl chloride could also be used though the yield was lower. A possible Pd(II)/Pd(IV) catalytic pathway involved in this coupling reaction was proposed.

KW - Coupling

KW - Enamide

KW - Palladium

KW - Sulfonylation

KW - Vinyl pyridine

UR - http://www.scopus.com/inward/record.url?scp=84876694375&partnerID=8YFLogxK

U2 - 10.1016/j.tet.2013.01.071

DO - 10.1016/j.tet.2013.01.071

M3 - 文章

AN - SCOPUS:84876694375

SN - 0040-4020

VL - 69

SP - 4403

EP - 4407

JO - Tetrahedron

JF - Tetrahedron

IS - 22

ER -

Palladium-catalyzed alkenyl C-H bond sulfonylation reaction using organosulfonyl chlorides

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this