Solvothermal synthesis, crystal structure, and properties of a new organictemplated holmium sulfate with ID single ladder chains

Wanli Zhou; Xiaorun Ding; Zhibin Zhang; Lei Zheng; Yan Xu; Dunru Zhu

doi:10.1002/zaac.200900397

Solvothermal synthesis, crystal structure, and properties of a new organictemplated holmium sulfate with ID single ladder chains

Wanli Zhou, Xiaorun Ding, Zhibin Zhang, Lei Zheng, Yan Xu, Dunru Zhu

College of Chemical Engineering

Research output: Contribution to journal › Article › peer-review

18 Scopus citations

Abstract

A new organic amine templated ID holmium sulfate (C₂H ₈N)[Ho(SO₄)₂·H₂O] (1) has been, synthesized and solvothermally and structurally characterized by single-crystal X-ray diffraction, IR spectroscopy, thermogravimetric and X-ray diffraction analyses as well as scanning electron microscopy (SEM). The structure of framework 1 is constructed from HoO₈ polyhedra and SO₄ tetrahedra. S(1) and S(2) connects Ho(1) and its crystallographic partners by using three S-O-Ho linkages to generate double chains, whereas the adjacent double chain are connected by μ₃-O (O₅) atoms to form a novel single ladder chains.

Original language	English
Pages (from-to)	882-885
Number of pages	4
Journal	Zeitschrift fur Anorganische und Allgemeine Chemie
Volume	636
Issue number	5
DOIs	https://doi.org/10.1002/zaac.200900397
State	Published - Apr 2010

Keywords

Electron microscopy
Holmium
Ir spectroscopy
Rare earths
Solvothermal synthesis

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title = "Solvothermal synthesis, crystal structure, and properties of a new organictemplated holmium sulfate with ID single ladder chains",

abstract = "A new organic amine templated ID holmium sulfate (C2H 8N)[Ho(SO4)2·H2O] (1) has been, synthesized and solvothermally and structurally characterized by single-crystal X-ray diffraction, IR spectroscopy, thermogravimetric and X-ray diffraction analyses as well as scanning electron microscopy (SEM). The structure of framework 1 is constructed from HoO8 polyhedra and SO4 tetrahedra. S(1) and S(2) connects Ho(1) and its crystallographic partners by using three S-O-Ho linkages to generate double chains, whereas the adjacent double chain are connected by μ3-O (O5) atoms to form a novel single ladder chains.",

keywords = "Electron microscopy, Holmium, Ir spectroscopy, Rare earths, Solvothermal synthesis",

author = "Wanli Zhou and Xiaorun Ding and Zhibin Zhang and Lei Zheng and Yan Xu and Dunru Zhu",

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language = "英语",

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TY - JOUR

T1 - Solvothermal synthesis, crystal structure, and properties of a new organictemplated holmium sulfate with ID single ladder chains

AU - Zhou, Wanli

AU - Ding, Xiaorun

AU - Zhang, Zhibin

AU - Zheng, Lei

AU - Xu, Yan

AU - Zhu, Dunru

PY - 2010/4

Y1 - 2010/4

N2 - A new organic amine templated ID holmium sulfate (C2H 8N)[Ho(SO4)2·H2O] (1) has been, synthesized and solvothermally and structurally characterized by single-crystal X-ray diffraction, IR spectroscopy, thermogravimetric and X-ray diffraction analyses as well as scanning electron microscopy (SEM). The structure of framework 1 is constructed from HoO8 polyhedra and SO4 tetrahedra. S(1) and S(2) connects Ho(1) and its crystallographic partners by using three S-O-Ho linkages to generate double chains, whereas the adjacent double chain are connected by μ3-O (O5) atoms to form a novel single ladder chains.

AB - A new organic amine templated ID holmium sulfate (C2H 8N)[Ho(SO4)2·H2O] (1) has been, synthesized and solvothermally and structurally characterized by single-crystal X-ray diffraction, IR spectroscopy, thermogravimetric and X-ray diffraction analyses as well as scanning electron microscopy (SEM). The structure of framework 1 is constructed from HoO8 polyhedra and SO4 tetrahedra. S(1) and S(2) connects Ho(1) and its crystallographic partners by using three S-O-Ho linkages to generate double chains, whereas the adjacent double chain are connected by μ3-O (O5) atoms to form a novel single ladder chains.

KW - Electron microscopy

KW - Holmium

KW - Ir spectroscopy

KW - Rare earths

KW - Solvothermal synthesis

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DO - 10.1002/zaac.200900397

M3 - 文章

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Solvothermal synthesis, crystal structure, and properties of a new organictemplated holmium sulfate with ID single ladder chains

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