Solvothermal synthesis, crystal structure, and properties of a new organictemplated holmium sulfate with ID single ladder chains

Wanli Zhou, Xiaorun Ding, Zhibin Zhang, Lei Zheng, Yan Xu, Dunru Zhu

Research output: Contribution to journalArticlepeer-review

18 Scopus citations

Abstract

A new organic amine templated ID holmium sulfate (C2H 8N)[Ho(SO4)2·H2O] (1) has been, synthesized and solvothermally and structurally characterized by single-crystal X-ray diffraction, IR spectroscopy, thermogravimetric and X-ray diffraction analyses as well as scanning electron microscopy (SEM). The structure of framework 1 is constructed from HoO8 polyhedra and SO4 tetrahedra. S(1) and S(2) connects Ho(1) and its crystallographic partners by using three S-O-Ho linkages to generate double chains, whereas the adjacent double chain are connected by μ3-O (O5) atoms to form a novel single ladder chains.

Original languageEnglish
Pages (from-to)882-885
Number of pages4
JournalZeitschrift fur Anorganische und Allgemeine Chemie
Volume636
Issue number5
DOIs
StatePublished - Apr 2010

Keywords

  • Electron microscopy
  • Holmium
  • Ir spectroscopy
  • Rare earths
  • Solvothermal synthesis

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