Abstract
A new organic amine templated ID holmium sulfate (C2H 8N)[Ho(SO4)2·H2O] (1) has been, synthesized and solvothermally and structurally characterized by single-crystal X-ray diffraction, IR spectroscopy, thermogravimetric and X-ray diffraction analyses as well as scanning electron microscopy (SEM). The structure of framework 1 is constructed from HoO8 polyhedra and SO4 tetrahedra. S(1) and S(2) connects Ho(1) and its crystallographic partners by using three S-O-Ho linkages to generate double chains, whereas the adjacent double chain are connected by μ3-O (O5) atoms to form a novel single ladder chains.
Original language | English |
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Pages (from-to) | 882-885 |
Number of pages | 4 |
Journal | Zeitschrift fur Anorganische und Allgemeine Chemie |
Volume | 636 |
Issue number | 5 |
DOIs | |
State | Published - Apr 2010 |
Keywords
- Electron microscopy
- Holmium
- Ir spectroscopy
- Rare earths
- Solvothermal synthesis