Solvothermal synthesis, crystal structure, and properties of a new organictemplated holmium sulfate with ID single ladder chains

Wanli Zhou; Xiaorun Ding; Zhibin Zhang; Lei Zheng; Yan Xu; Dunru Zhu

doi:10.1002/zaac.200900397

Solvothermal synthesis, crystal structure, and properties of a new organictemplated holmium sulfate with ID single ladder chains

Wanli Zhou, Xiaorun Ding, Zhibin Zhang, Lei Zheng, Yan Xu, Dunru Zhu

化工学院

科研成果: 期刊稿件 › 文章 › 同行评审

18 引用（Scopus）

摘要

A new organic amine templated ID holmium sulfate (C₂H ₈N)[Ho(SO₄)₂·H₂O] (1) has been, synthesized and solvothermally and structurally characterized by single-crystal X-ray diffraction, IR spectroscopy, thermogravimetric and X-ray diffraction analyses as well as scanning electron microscopy (SEM). The structure of framework 1 is constructed from HoO₈ polyhedra and SO₄ tetrahedra. S(1) and S(2) connects Ho(1) and its crystallographic partners by using three S-O-Ho linkages to generate double chains, whereas the adjacent double chain are connected by μ₃-O (O₅) atoms to form a novel single ladder chains.

源语言	英语
页（从-至）	882-885
页数	4
期刊	Zeitschrift fur Anorganische und Allgemeine Chemie
卷	636
期	5
DOI	https://doi.org/10.1002/zaac.200900397
出版状态	已出版 - 4月 2010

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title = "Solvothermal synthesis, crystal structure, and properties of a new organictemplated holmium sulfate with ID single ladder chains",

abstract = "A new organic amine templated ID holmium sulfate (C2H 8N)[Ho(SO4)2·H2O] (1) has been, synthesized and solvothermally and structurally characterized by single-crystal X-ray diffraction, IR spectroscopy, thermogravimetric and X-ray diffraction analyses as well as scanning electron microscopy (SEM). The structure of framework 1 is constructed from HoO8 polyhedra and SO4 tetrahedra. S(1) and S(2) connects Ho(1) and its crystallographic partners by using three S-O-Ho linkages to generate double chains, whereas the adjacent double chain are connected by μ3-O (O5) atoms to form a novel single ladder chains.",

keywords = "Electron microscopy, Holmium, Ir spectroscopy, Rare earths, Solvothermal synthesis",

author = "Wanli Zhou and Xiaorun Ding and Zhibin Zhang and Lei Zheng and Yan Xu and Dunru Zhu",

year = "2010",

month = apr,

doi = "10.1002/zaac.200900397",

language = "英语",

volume = "636",

pages = "882--885",

journal = "Zeitschrift fur Anorganische und Allgemeine Chemie",

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T1 - Solvothermal synthesis, crystal structure, and properties of a new organictemplated holmium sulfate with ID single ladder chains

AU - Zhou, Wanli

AU - Ding, Xiaorun

AU - Zhang, Zhibin

AU - Zheng, Lei

AU - Xu, Yan

AU - Zhu, Dunru

PY - 2010/4

Y1 - 2010/4

N2 - A new organic amine templated ID holmium sulfate (C2H 8N)[Ho(SO4)2·H2O] (1) has been, synthesized and solvothermally and structurally characterized by single-crystal X-ray diffraction, IR spectroscopy, thermogravimetric and X-ray diffraction analyses as well as scanning electron microscopy (SEM). The structure of framework 1 is constructed from HoO8 polyhedra and SO4 tetrahedra. S(1) and S(2) connects Ho(1) and its crystallographic partners by using three S-O-Ho linkages to generate double chains, whereas the adjacent double chain are connected by μ3-O (O5) atoms to form a novel single ladder chains.

AB - A new organic amine templated ID holmium sulfate (C2H 8N)[Ho(SO4)2·H2O] (1) has been, synthesized and solvothermally and structurally characterized by single-crystal X-ray diffraction, IR spectroscopy, thermogravimetric and X-ray diffraction analyses as well as scanning electron microscopy (SEM). The structure of framework 1 is constructed from HoO8 polyhedra and SO4 tetrahedra. S(1) and S(2) connects Ho(1) and its crystallographic partners by using three S-O-Ho linkages to generate double chains, whereas the adjacent double chain are connected by μ3-O (O5) atoms to form a novel single ladder chains.

KW - Electron microscopy

KW - Holmium

KW - Ir spectroscopy

KW - Rare earths

KW - Solvothermal synthesis

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U2 - 10.1002/zaac.200900397

DO - 10.1002/zaac.200900397

M3 - 文章

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JO - Zeitschrift fur Anorganische und Allgemeine Chemie

JF - Zeitschrift fur Anorganische und Allgemeine Chemie

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Solvothermal synthesis, crystal structure, and properties of a new organictemplated holmium sulfate with ID single ladder chains

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