Palladium-Catalyzed Regioselective Olefination of O-Acetyl Cyanohydrins

Qiu Ju Liang; Bing Jiang; Yun He Xu; Teck Peng Loh

doi:10.1021/acs.joc.8b00991

Palladium-Catalyzed Regioselective Olefination of O-Acetyl Cyanohydrins

Qiu Ju Liang, Bing Jiang, Yun He Xu, Teck Peng Loh

科研成果: 期刊稿件 › 文章 › 同行评审

10 引用（Scopus）

摘要

A practical palladium-catalyzed ortho-olefination of O-acetyl cyanohydrins assisted by synergetic directing groups has been developed. Thus, a range of olefinated O-acetyl cyanohydrins were synthesized in moderate to good yields. The reaction occurs efficiently with high regioselectivity and with a satisfactory tolerance of functional groups.

源语言	英语
页（从-至）	8265-8271
页数	7
期刊	Journal of Organic Chemistry
卷	83
期	15
DOI	https://doi.org/10.1021/acs.joc.8b00991
出版状态	已出版 - 3 8月 2018
已对外发布	是

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abstract = "A practical palladium-catalyzed ortho-olefination of O-acetyl cyanohydrins assisted by synergetic directing groups has been developed. Thus, a range of olefinated O-acetyl cyanohydrins were synthesized in moderate to good yields. The reaction occurs efficiently with high regioselectivity and with a satisfactory tolerance of functional groups.",

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AB - A practical palladium-catalyzed ortho-olefination of O-acetyl cyanohydrins assisted by synergetic directing groups has been developed. Thus, a range of olefinated O-acetyl cyanohydrins were synthesized in moderate to good yields. The reaction occurs efficiently with high regioselectivity and with a satisfactory tolerance of functional groups.

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Palladium-Catalyzed Regioselective Olefination of O-Acetyl Cyanohydrins

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