Synthetic studies toward anisatin: A formal synthesis of (±)-8-deoxyanisatin

Teck Peng Loh; Qi Ying Hu

doi:10.1021/ol006918c

Synthetic studies toward anisatin: A formal synthesis of (±)-8-deoxyanisatin

Teck Peng Loh, Qi Ying Hu

National University of Singapore

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41 引用（Scopus）

摘要

equations presented An efficient strategy to construct the congested C-7a quaternary chiral center of anisatin was developed, by way of an Eschenmoser-Claisen rearrangement. Conversion of the resultant amide to Kende's ε-lactone intermediate 3 in four steps completed a concise formal synthesis of (±)-8-deoxyanisatin (2).

源语言	英语
页（从-至）	279-281
页数	3
期刊	Organic Letters
卷	3
期	2
DOI	https://doi.org/10.1021/ol006918c
出版状态	已出版 - 25 1月 2001
已对外发布	是

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10.1021/ol006918c

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title = "Synthetic studies toward anisatin: A formal synthesis of (±)-8-deoxyanisatin",

abstract = "equations presented An efficient strategy to construct the congested C-7a quaternary chiral center of anisatin was developed, by way of an Eschenmoser-Claisen rearrangement. Conversion of the resultant amide to Kende's ε-lactone intermediate 3 in four steps completed a concise formal synthesis of (±)-8-deoxyanisatin (2).",

author = "Loh, {Teck Peng} and Hu, {Qi Ying}",

year = "2001",

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N2 - equations presented An efficient strategy to construct the congested C-7a quaternary chiral center of anisatin was developed, by way of an Eschenmoser-Claisen rearrangement. Conversion of the resultant amide to Kende's ε-lactone intermediate 3 in four steps completed a concise formal synthesis of (±)-8-deoxyanisatin (2).

AB - equations presented An efficient strategy to construct the congested C-7a quaternary chiral center of anisatin was developed, by way of an Eschenmoser-Claisen rearrangement. Conversion of the resultant amide to Kende's ε-lactone intermediate 3 in four steps completed a concise formal synthesis of (±)-8-deoxyanisatin (2).

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Synthetic studies toward anisatin: A formal synthesis of (±)-8-deoxyanisatin

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