The reactivity of [Zn2Cp*2]: Trapping monovalent {.ZnZnCp*} in the metal-rich compounds [(Pd,Pt)(GaCp*)a(ZnCp*)4-a(ZnZnCp*) 4-a] (a=0, 2)

Timo Bollermann, Kerstin Freitag, Christian Gemel, Rüdiger W. Seidel, Moritz Von Hopffgarten, Gernot Frenking, Roland A. Fischer

科研成果: 期刊稿件文章同行评审

46 引用 (Scopus)

摘要

Inseparable zinc pair: The reaction of homoleptic {GaCp*}-containing compounds [M(GaCp*)4] (M=Pd, Pt; Cp*=Me5C 5) with [Zn2Cp*2] leads to the formation of [M(GaCp*)2(ZnCp*)2(ZnZnCp*) 2] (see picture: C gray, Ga yellow, Zn green, Pd blue) and [M(ZnCp*)4(ZnZnCp*)4]. Both molecules involve the novel zinc ligand system {ZnZnCp*}, which contains an intact Zn-Zn bond.

源语言英语
页(从-至)772-776
页数5
期刊Angewandte Chemie - International Edition
50
3
DOI
出版状态已出版 - 17 1月 2011
已对外发布

指纹

探究 'The reactivity of [Zn2Cp*2]: Trapping monovalent {.ZnZnCp*} in the metal-rich compounds [(Pd,Pt)(GaCp*)a(ZnCp*)4-a(ZnZnCp*) 4-a] (a=0, 2)' 的科研主题。它们共同构成独一无二的指纹。

引用此